Polymorphism in the Mg3BPO7–Ni3BPO7 System
- Authors: Smirnova M.N.1, Kop’eva M.A.1, Nipan G.D.1, Nikiforova G.E.1, Yapryntsev A.D.1, Arkhipenko A.A.1, Doronina M.S.2
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Issue: Vol 68, No 6 (2023)
- Pages: 746-751
- Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
- URL: https://journals.rcsi.science/0044-457X/article/view/136466
- DOI: https://doi.org/10.31857/S0044457X2260236X
- EDN: https://elibrary.ru/UFWYXL
- ID: 136466
Cite item
Abstract
The Mg3 – nNinBPO7 (n = 0.0, 0.5, 1.0, 1.5, 2.0, 2.5, and 3.0) samples were prepared by solid-phase reactions at 980°C followed by inertial cooling, and then were characterized by X-ray powder diffraction, IR spectroscopy, diffusive reflectance and X-ray fluorescence spectrometry. It was for the first time that experiments yielded Ni3BPO7 crystals having the β-Zn3BPO7 non-centrosymmetrical hexagonal structure. The α-Mg3BPO7 and Ni3BPO7 coexistence range was determined. The diffuse reflectance spectra of an Mg1.5Ni1.5BPO7 sample featured a strong Ni2+ absorption band in the blue spectral range.
Keywords
About the authors
M. N. Smirnova
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: smirnova_macha1989@mail.ru
Russian Federation, 119991, Moscow
M. A. Kop’eva
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: smirnova_macha1989@mail.ru
Russian Federation, 119991, Moscow
G. D. Nipan
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: gbuzanov@yandex.ru
Russian Federation, 119071, Moscow
G. E. Nikiforova
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: smirnova_macha1989@mail.ru
Russian Federation, 119991, Moscow
A. D. Yapryntsev
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: smirnova_macha1989@mail.ru
Russian Federation, 119991, Moscow
A. A. Arkhipenko
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: smirnova_macha1989@mail.ru
Russian Federation, 119991, Moscow
M. S. Doronina
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: alexandra622@mail.ru
119071, Moscow, Russia
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