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Phase Formation in the MgO–B2O3–P2O5 System

  • PHYSICOCHEMICAL ANALYSIS OF INORGANIC SYSTEMS
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Abstract

Mg1 – x(BP)x/2O1 + x, Mg3B2 – 2xP2xO6 + 2x, Mg2B2 – 2xP2xO5 + 2x, and MgB2 – 2xP2xO4 + x (0 ≤ х ≤ 1, х = 0.1 step) samples prepared by gel combustion or solid-phase sintering and then annealed at 1000°C were characterized by X-ray powder diffraction. An Mg3BPO7 crystal phase was prepared and characterized by IR spectroscopy and scanning electron microscopy. Stable and metastable equilibrium phase diagrams were plotted for the 2MgO–B2O3–P2O5 quasi-ternary system.

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ACKNOWLEDGMENTS

Facilities of the Shared Facilities Center of the Kurnakov Instituted of General and Inorganic Chemistry of the Russian Academy of Sciences were used in the work.

Funding

This work was supported by the Ministry of Education and Science of Russia through the Government Assignment to the Kurnakov Instituted of General and Inorganic Chemistry of the Russian Academy of Sciences.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    M. N. Smirnova, M. A. Kop’eva, G. D. Nipan & G. E. Nikiforova

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  1. M. N. Smirnova
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  2. M. A. Kop’eva
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  3. G. D. Nipan
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  4. G. E. Nikiforova
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Correspondence to M. N. Smirnova.

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Translated by O. Fedorova

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Smirnova, M.N., Kop’eva, M.A., Nipan, G.D. et al. Phase Formation in the MgO–B2O3–P2O5 System. Russ. J. Inorg. Chem. 67, 1823–1830 (2022). https://doi.org/10.1134/S0036023622600824

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  • DOI: https://doi.org/10.1134/S0036023622600824

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