Investigation of the Pore Structure of Exfoliated Graphite Based on Highly Oriented Pyrolytic Graphite Nitrate

A. V. Krautsou; Кравцов А. В.; O. N. Shornikova; Шорникова О. Н.; A. I. Bulygina; Булыгина А. И.; A. B. Solopov; Солопов А. Б.; A. L. Kustov; Кустов А. Л.; V. V. Avdeev; Авдеев В. В.

doi:10.31857/S0044453723060122

Investigation of the Pore Structure of Exfoliated Graphite Based on Highly Oriented Pyrolytic Graphite Nitrate

Authors: Krautsou A.V.¹, Shornikova O.N.¹, Bulygina A.I.¹, Solopov A.B.², Kustov A.L.¹, Avdeev V.V.¹
Affiliations:
1. Department of Chemistry, Moscow State University
2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Issue: Vol 97, No 6 (2023)
Pages: 827-835
Section: СТРОЕНИЕ ВЕЩЕСТВА И КВАНТОВАЯ ХИМИЯ
URL: https://journals.rcsi.science/0044-4537/article/view/136622
DOI: https://doi.org/10.31857/S0044453723060122
EDN: https://elibrary.ru/JIJQQW
ID: 136622

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

Graphite intercalated compounds (GICs) with different stage numbers were prepared from highly oriented pyrolytic graphite (HOPG) and nitric acid using a chemical method. Exfoliated graphite (EG-T) was synthesized from GICs by water treatment followed by thermal shock. The effects of the graphite oxidation depth on the EG-T thermal expansion coefficient, volatile content, and total porosity were examined. However, the main purpose of this work was investigation of the dependence of the inner EG-T pore structure on the level of oxidation. Thus, we studied the micro- and mesopore structure and specific surface area by nitrogen porosimetry and the modern 2D-NLDFT method to calculate the pore size distribution and pore volume. As well, we performed a mercury porosimetry experiment to determine the macropore characteristics. We examined the pore space using a number of scanning electron micrographs of EG-T particle cross-sections using an image processing technique. In this way we showed the strong correlation between the EG-T pore structure parameters and oxidation depth of graphite.

Keywords

exfoliated graphite, expandable graphite, HOPG, pore structure, 2D-NLDFT, MDFT

References

Chung D.D.L. // J. Mater. Sci. 2016. V. 51. P. 554. https://doi.org/10.1007/s10853-015-9284-6
Inagaki M., Kang F., Toyoda M. et al. // Advanced Materials Science and Engineering of Carbon, Butterworth-Heinemann. 2014. P. 313. https://doi.org/10.1016/B978-0-12-407789-8.00014-4
Wang Z., Han E., Ke W. // Corros. Sci. 2007. V. 49. P. 2237. https://doi.org/10.1016/j.corsci.2006.10.024
Song L.N., Xiao M., Meng Y.Z. // Compos. Sci. Technol. 2006. V. 66. P. 2156. https://doi.org/10.1016/j.compscitech.2005.12.013
Sorokina N.E., Redchitz A.V., Ionov S.G. et al. // J. Phys. Chem. Solids. 2006. V. 67. P. 1202. https://doi.org/10.1016/j.jpcs.2006.01.048
Nayak S.K., Mohanty S., Nayak S.K. // High Perform. Polym. 2019. V. 32. P. 506. https://doi.org/10.1177/0954008319884616
Sorokina N.E., Maksimova N.V., Avdeev V.V. // Inorg. Mater. 2001. V. 37. P. 360. https://doi.org/10.1023/A:1017575710886
Ivanov A.V., Maksimova N.V., Kamaev A.O. et al. // Mater. Lett. 2018. V. 228. P. 403. https://doi.org/10.1016/j.matlet.2018.06.072
Afanasov I.M., Shornikova O.N., Kirilenko D.A. et al. // Carbon. 2010. V. 48. P. 1862. https://doi.org/10.1016/j.carbon.2010.01.055
Forsman W.C., Vogel F.L., Carl D.E. et al. // Ibid. 1978. V. 16. P. 269. https://doi.org/10.1016/0008-6223(78)90040-4
Sorokina N.E., Maksimova N.V., Avdeev V.V. // Inorg. Mater. 2002. V. 38. P. 564. https://doi.org/10.1023/A:1015857317487
Salvatore M., Carotenuto G., De Nicola S. et al. // Nanoscale Res. Lett. 2017. V. 12. P. 167. https://doi.org/10.1186/s11671-017-1930-2
Dimiev A.M., Shukhina K., Behabtu N. et al. // J. Phys. Chem. C. 2019. V. 123. P. 19246. https://doi.org/10.1021/acs.jpcc.9b06726
Sorokina N.E., Monyakina L.A., Maksimova N.V. et al. // Inorg. Mater. 2002. V. 38. P. 482. https://doi.org/10.1023/A:1015423105964
Leshin V.S., Sorokina N.E., Avdeev V.V. // Ibid. 2004. V. 40. P. 649. https://doi.org/10.1023/B:INMA.0000032001.86743.00
Dunaev A.V., Arkhangelsky I.V., Zubavichus Y.V. et al. // Carbon. 2008. V. 46. P. 788. https://doi.org/10.1016/j.carbon.2008.02.003
Gurzęda B., Buchwald T., Krawczyk P. // J. Solid State Electrochem. 2020. V. 24. P. 1363. https://doi.org/10.1007/s10008-020-04642-x
Efimova E.A., Syrtsova D.A., Teplyakov V.V. // Sep. Purif. Technol. 2017. V. 179. P. 467. https://doi.org/10.1016/j.seppur.2017.02.023
Bodzenta J., Mazur J., Kaźmierczak-Bałata A. // Appl. Phys. B. 2011. V. 105. P. 623. https: //doi.org/.https://doi.org/10.1007/s00340-011-4510-7
Afanasov I.M., Makarenko I.V., Vlasov I.I. et al. // Compact. Expand. Graph. with a Low Therm. Conduct., Curran Associates, Inc., Clemson, South Carolina, USA. 2010: P. 645.
Ivanov A.V., Manylov M.S., Maksimova N.V. et al. // J. Mater. Sci. 2019. V. 54. P. 4457. https://doi.org/10.1007/s10853-018-3151-1
Inagaki M., Tashiro R., Toyoda M. et al. // Ceram. Soc. Jpn. 2004. V. 112-1. P. S1513. https://doi.org/10.14852/jcersjsuppl.112.0.S1513.0
Kang F., Zheng Y.-P., Wang H.-N. et al. // Carbon. 2002. V. 40. P. 1575. https://doi.org/10.1016/S0008-6223(02)00023-4
Inagaki M., Tashiro R., Washino Y. et al. // J. Phys. Chem. Solids. 2004. V. 65. P. 133. https://doi.org/10.1016/j.jpcs.2003.10.007
Inagaki M., Suwa T. // Carbon. 2001. V. 39. P. 915. https://doi.org/10.1016/S0008-6223(00)00199-8
Inagaki M., Saji N., Zheng Y.-P. et al. // TANSO. 2004. V. 2004. P. 258. https://doi.org/10.7209/tanso.2004.258
Tryba B., Morawski A.W., Kaleńczuk R.J. et al. // Spill Sci. Technol. Bull. 2003. V. 8. P. 569. https://doi.org/10.1016/S1353-2561(03)00070-7
Shornikova O.N., Kogan E.V., Petrov D.V. et al. // Pore structure of exfoliated graphite, Curran Associates, Inc., Clemson, South Carolina, USA. 2010: P. 421.
Goudarzi R., Hashemi Motlagh G. // Heliyon. 2019. V. 5. P. e02595. https://doi.org/10.1016/j.heliyon.2019.e02595
Bogdanov S.G., Valiev E.Z., Dorofeev Y.A. et al. // Cryst. Rep. 2006. V. 51. P. S12. https://doi.org/10.1134/S1063774506070030
Sorokina N.E., Monyakina L.A., Maksimova N.V. et al. // Inorg. Mater. 2002. V. 38. P. 482. https://doi.org/10.1023/A:1015423105964
Sorokina N.E., Nikol’skaya I.V., Ionov S.G. et al. // Russ. Chem. Bull. 2005. V. 54. P. 1749. https://doi.org/10.1007/s11172-006-0034-4
Sing K.S.W. // Pure Appl. Chem. 1982. V. 54. P. 2201. https://doi.org/10.1351/pac198254112201
Jagiello J., Olivier J.P. // Carbon. 2012. V. 55. P. 70. https://doi.org/10.1016/j.carbon.2012.12.011
Jagiello J., Olivier J.P. // J. Phys. Chem. C. 2009. V. 113. P. 19382. https://doi.org/10.1021/jp9082147
Ross S., Olivier J.P. // J. Phys. Chem. 1961. V. 65. P. 608. https://doi.org/10.1021/j100822a005
Olivier J.P., Winter M. // J. Power Sources. 2001. V. 97–98. P. 151. https://doi.org/10.1016/S0378-7753(01)00527-4
Li Z., Peng H., Liu R. et al. // J. Power Sources. 2020. V. 457. P. 228022. https://doi.org/10.1016/j.jpowsour.2020.228022