Skip to main content
SpringerLink
Log in

Synthesis and structure of tri(o-tolyl) antimony dioximates

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Tri(o-tolyl) antimony dioximates were synthesized by the reaction of tri(o-tolyl) antimony with 5-nitrofurfural and thiophen-2-carbaldehyde oximes in ether in the presence of hydrogen peroxide or tert-butylhydroperoxide (1: 2: 1 mol). Antimony atoms in the reaction products have distorted trigonal-bipyramidal coordination with the intramolecular distances Sb···N shorter than the sum of the van der Waals radii of Sb and N by ~1 Å.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Tiekink, E.R.T., Crit. Rev Oncol. Hematol., 2002, vol. 42, no. 3, p. 217. doi 10.1016/S1040-8428(01)00217-7

    Article  Google Scholar 

  2. Ozturk, I.I., Banti, C.N., Manos, M.J., Tasiopoulos, A.J., Kourkoumelis, N., Charalabopoulos, K., and Hadjikakou, S.K., J. Inorg. Biochem., 2012, vol. 109, p. 57. doi 10.1016/j.jinorgbio.2012.01.014

    Article  CAS  Google Scholar 

  3. Ali, M.I., Rauf, M.K., Badshah, A., Kumar, I., Forsyth, C.M., Junk, P.C., Kedzierski, L., and Andrews, P.C., Dalton Trans., 2013, vol. 42, no. 1, p. 16733. doi 10.1039/C3DT51382C

    Article  CAS  Google Scholar 

  4. Yu, L., Ma, Y.-Q., Wang, G.-C., and Li, J.-S., Heteroatom Chem., 2004, vol. 15, p. 32. doi DOI/hc.10208

    Article  CAS  Google Scholar 

  5. Bajpai, K. and Srivastava, R.C., Synth. Inorg. Met.-Org. Chem., 1981, vol. 11, no. 1, p. 7. doi 10.1080/00945718108059270

    Article  CAS  Google Scholar 

  6. Nakamura, H., Iitaka, Y., Sakakibara, H., and Umezawa, H., J. Antibiotics, 1974, no. 27, p. 894. doi 10.7164/antibiotics.6. 27.894

    Article  CAS  Google Scholar 

  7. Handong, Y., Li, Q, and Linwei, L., Inorg. Chem. Commun., 2008, no. 11, p. 1121. doi 10.1016/j.inoche.2008.06.017

    Article  Google Scholar 

  8. Gupta, A., Sharma, R.K., Bohra, R., Jain, V.K., Drake, J.E., Hursthouse, M.B., and Light, M.E., Polyhedron, 2002, vol. 21, no. 23, p. 2387. doi 10.1016/S0277-5387(02)01155-5

    Article  CAS  Google Scholar 

  9. Sharutin, V.V., Sharutina, O.K., Molokova, O.V., Pakusina, A.P., Gerasimenko, A.V., and Gerasimenko, E.A., Russ. J. Coord. Chem., 2002, vol. 28, no. 7, p. 464. doi 10.1023/A:1016293009968

    Article  CAS  Google Scholar 

  10. Sharutin, V.V., Sharutina, O.K., Molokova, O.V., Pakusina, A.P., Gerasimenko, A.V., Sergienko, A.S., Bukvetskii, B.V., and Popov, D.Yu., Russ. J. Coord. Chem., 2002, vol. 28, no. 8, p. 544. doi 10.1023/A:1019701511840

    Article  CAS  Google Scholar 

  11. Dodonov, V.A, Gushchin, A.V., Gor’kaev, D.A., Fukin, G.K., Starostina, T.I., Zakharov, L.N., Kurskii, Ju.A., and Shavyrin, A.S., Russ. Chem. Bull., 2002, no. 6, p. 1051. doi 10.1023/A:1019634307064

    Article  Google Scholar 

  12. Sharutin, V.V., Sharutina, O.K., Molokova, O.V., Pakusina, A.P., Bondar’, E.A., Krivolapov, D.B., Gubaidullin, A.T., and Litvinov, I.A., Russ. J. Gen. Chem., 2001, vol. 71, no. 9, p. 1426. doi 10.1023/A:1013910120594

    Article  CAS  Google Scholar 

  13. Sharutin, V.V., Molokova, O.V., Sharutina, O.K., and Smirnova, S.A., Russ. J. Inorg. Chem., 2012, vol. 57, no. 9, p. 1252. doi 10.1134/S0036023612090185

    Article  CAS  Google Scholar 

  14. Dong, L., Yin, H., Wen, L., and Wang, D., Acta Cryst.(E), 2009, vol. 65, no. 11, p. m1438. doi 10.1107/S1600536809043542

    Google Scholar 

  15. Sharutin, V.V., Sharutina, O.K., Artem’eva, E.V., and Makerova, M.S., Vestn. YuUrGU, Ser. Khimiya, 2014, vol. 8, no. 2, p. 5.

    Google Scholar 

  16. Sharutin, V.V. and Sharutina, O.K., Russ. J. Inorg. Chem., 2014, vol. 59, no. 11, p. 1263. doi 10.1134/S0036023614110229

    Article  CAS  Google Scholar 

  17. Sharutin, V.V., Sharutina, O.K., Artem’eva, E.V., and Makerova, M.S., Russ. J. Inorg. Chem., 2015, vol. 60, no. 2, p. 207. doi 10.1134/S0036023615020138

    Google Scholar 

  18. Doak, G.O., Long, G.G., and Freedman, L.D., J. Organomet. Chem., 1965, vol. 4, no. 1, p. 82. doi 10.1016/S0022-328X(0000)823700-0

    Article  CAS  Google Scholar 

  19. Batsanov, S.S., Zh. Neorg. Khim., 1991, vol. 36, no. 12, p. 3015.

    CAS  Google Scholar 

  20. Bruker (1998). Smart and SAINT-Plus. Versions 5.0. Data Collection and Processing Software for the SMART System. Bruker AXS Inc., Madison, Wisconsin, USA.

  21. Bruker (1998). SHELXTL/PC. Versions 5.10. An Integrated System for Solving, Refining and Displaying Crystal Structures From Diffraction Data. Bruker AXS Inc., Madison, Wisconsin, USA.

Download references

Author information

Authors and Affiliations

  1. National Research South Ural State University, pr. Lenina 76, Chelyabinsk, 454080, Russia

    V. V. Sharutin, O. K. Sharutina, E. V. Artem’eva & M. S. Makerova

Authors
  1. V. V. Sharutin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. K. Sharutina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. V. Artem’eva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. S. Makerova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. V. Sharutin.

Additional information

Original Russian Text © V.V. Sharutin, O.K. Sharutina, E.V. Artem’eva, M.S. Makerova, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 12, pp. 2039–2044.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sharutin, V.V., Sharutina, O.K., Artem’eva, E.V. et al. Synthesis and structure of tri(o-tolyl) antimony dioximates. Russ J Gen Chem 86, 2671–2676 (2016). https://doi.org/10.1134/S1070363216120161

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363216120161

Keywords

Search

Navigation