Abstract
Reaction of triphenylstibine with furfuraloxime in the presence of hydrogen peroxide in water-ether solution forms μ-oxobis[triphenyl(furfuraloximato)antimony(V)] in 90% yield. This complex has a dimeric structure in which two antimony atoms are bound with the bridge oxygen atom and two bridge oxime groups coordinating the metal atom by the oxygen as well as by the nitrogen atoms to form bicyclo[2.2.1]heptane fragment. SbOSb angle is 125.5(3)°, the bonds between the antimony atom and the bridge oxygen atoms [1.957(6) and 1.946(5) Å] are shorter than with the oxygen atoms of oxime groups [2.146(6) and 2.148(6) Å].
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REFERENCES
Ferguson, G. and Ridley, D.R., Acta Crys. (B), 1973, vol. 29, no. 10, pp. 2221–2226.
Starikova, Z.A., Shchegoleva, T.M., Trunov, V.K., and Pokrovskaya, I.E., Kristallogr., 1978, vol. 23, no. 5, pp.969–973.
Breneman, G.L., Acta Cryst. (B), 1979, vol. 35, no. 4, pp. 731–735.
Preut, H., Ruther, R., and Huber, F., Acta Cryst. (C), 1985, vol. 41, no. 2, pp. 358–359.
Preut, H., Ruther, R., and Huber, F., Acta Cryst. (C), 1986, vol. 42, no. 6, pp. 1154–1155.
Ruther, R., Huber, F., and Preut, H., Angew Chem., Int. Ed. Enlg., 1987, vol. 26, no. 8, pp. 906–908.
Tiekink, E.R.T., J. Organomet. Chemn., 1987, vol. 333, no. 1, pp. 199–203.
Ouchi, A. and Sato, S., Bull Chem. Soc. Japan, 1988, vol. 61, no. 11, pp. 1806–1808.
Taylor, M.J., Baker, L.–J., Rickard, C.E.E., and Surman, P.W.L., J. Organomet. Chem., 1995, vol. 498, no. 1, pp. C14–16.
Almond, M.J., Drew, M.G.B., Rice, D.A., Salisbury, G., and Taylor, M.J., J. Organomet. Chem., 1996, vol. 522, no. 2, pp. 265–268.
Sharutin, V.V., Sharutina, O.K., Panova, L.P., Nasonova, N.V., Bliznyuk, T.N., and Bel'skii, V.K., Izv. Akad. Nauk, Ser. Khim., 1999, no. 1, pp. 174–176.
Sharutin, V.V., Sharutina, O.K., Nasonova, N.V., Ivashchik, I.A., Krivolapov, D.B., Gubaidullin, A.T., and Litvinov, I.A., Izv. Ross. Akad. Nauk, Ser. Khim., 2000, no. 12, pp. 2346–2349.
Ferguson, G. and Hawley, D.M., Acta Cryst. (B), 1974, vol. 30, no. 1, pp. 103–111.
Mashon, M.F., Molloy, K.C., Omotowa, B.A., and Mesubi, M.A, J. Organomet. Chem., 1998, vol. 560, no. 1, pp. 95–101.
Bordner, J., Doak, G.O., and Everett, T.S., J. Am. Chem. Soc., 1986, vol. 108, no. 26, pp. 42064–4206.
Edwarda, A.J., Paver, M.A., Pearson, P., Raithby, P.R., Rennie, M.–A., Russell, C.A., and Wright, D.C.,J. Organomet. Chem., 1995, vol. 503, no. 1, pp. C29–C31.
Altomare, A., Cascarano, G., Giacovazzo, C., and Virerbo, D., Acta Cryst. (A), 1991, vol. 47, no. 4, pp. 744–748.
Straver, L.H. and Schierbeek, A.J., MolEN Structure Determination System, Nonius, B.V., 1994, vols. 1, 2.
Spek, A.L., Acta Cryst. (A), 1990, vol. 46, no. 1, pp. 34–36
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Sharutin, V.V., Sharutina, O.K., Molokova, O.V. et al. Synthesis and Structure of μ-Oxobis[triphenyl(furfuraloximato)antimony(V)]. Russian Journal of General Chemistry 71, 1426–1430 (2001). https://doi.org/10.1023/A:1013910120594
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DOI: https://doi.org/10.1023/A:1013910120594