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Specific features of the reaction between tris(5-bromo-2-methoxyphenyl)antimony and 2-oxybenzaldoxime: Structure of bis(μ3-2-oxybenzaldoximato-O,O′,N)-(μ2-oxo)-bis(5-bromo-2-methoxyphenyl)antimony

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Abstract

Bis(μ3-2-oxybenzaldoximato-O,O′,N)-(μ2-oxo)-bis(5-bromo-2-methoxyphenyl)antimony, which crystallizes from toluene in the form of a solvate, has been synthesized by the reaction between tris(5-bromo-2-methoxyphenyl)antimony and 2-oxybenzaldoxime in the presence of hydrogen peroxide. According to X-ray diffraction data, the structurally equivalent antimony atoms in a binuclear complex molecule are linked via two tridentate bridging ligands and an oxygen atom and have a distorted octahedral coordination to the C2O3N surrounding The trans-angles of the octahedron are CSbO (168.7(1)°), CSbN (164.1(1)°), and OSbO (159.3(1)°), and the bond lengths are Sb-C (2.127(4), 2.159(3) Å) and Sb-N (2.238(3) Å). A molecule contains the three types of Sb-O distances with a bridging oxygen atom (1.950(1) Å), the oxygen atoms of oxy groups (2.002(2) Å), and the oxygen atoms of oxime groups (2.091(2) Å). Sb⋯OCH3 intramolecular contacts (3.097, 3.290 Å) also exist.

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Authors and Affiliations

  1. National South Ural State Research University, pr. Lenina 76, Chelyabinsk, 454080, Russia

    V. V. Sharutin & O. K. Sharutina

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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Correspondence to V. V. Sharutin.

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Original Russian Text © V.V. Sharutin, O.K. Sharutina, 2014, published in Zhurnal Neorganicheskoi Khimii, 2014, Vol. 59, No. 11, pp. 1507–1511.

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Sharutin, V.V., Sharutina, O.K. Specific features of the reaction between tris(5-bromo-2-methoxyphenyl)antimony and 2-oxybenzaldoxime: Structure of bis(μ3-2-oxybenzaldoximato-O,O′,N)-(μ2-oxo)-bis(5-bromo-2-methoxyphenyl)antimony. Russ. J. Inorg. Chem. 59, 1263–1267 (2014). https://doi.org/10.1134/S0036023614110229

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  • DOI: https://doi.org/10.1134/S0036023614110229

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