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2022 Vol.54, Issue 4 Preview Page
Influence of Wood Pulp Properties on the Efficiency of Carboxymethylation

펄프 성상이 카르복시메틸레이션 유도체화 효율에 미치는 영향

Tai-Ju Lee1
,
Yujin Oh2
,
Jae-Gyoung Gwon1
,
Kyojung Hwang2
,
Ji-Soo Park2
,
Jinho Seo1†
이태주 1
,
오유진 2
,
권재경 1
,
황교정 2
,
박지수 2
,
서진호 1†
1Division of Forest Industrial Materials, Department of Forest Products and Industry, National Institute of Forest Science
2Division of Forest Industrial Materials, Department of Forest Products and Industry, National Institute of Forest Science
1국립산림과학원 임산자원이용연구부 임산소재연구과, 연구사
2국립산림과학원 임산자원이용연구부 임산소재연구과, 연구원
†Corresponding author: E-Mail: seojh97@korea.kr (Address: Division of Forest Industrial Materials, Department of Forest Products and Industry, National Institute of Forest Science, Seoul 02455, Republic of Korea)
30 August 2022. pp. 85-93
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Abstract

Wood pulp properties are important controlling parameters to produce cellulose derivatives because they could affect the chemical accessibility and reactivity. This study investigated the effect of wood pulp properties on the carboxymethylation of pulp cellulose using various cooking techniques and species-appropriates fractionations. The efficiency of carboxymethylation was improved with the increase in the alpha-cellulose of pulp because lignin and hemicellulose, which adversely affect derivatization, were removed. In the case of hardwood, the removal of the fines comprising vessel elements had a positive effect on the carboxymethylation. In the case of softwood, the narrow variance of fiber length and width by fractionation was positive in improving the efficiency of carboxymethylation. The highest carboxyl content was 2.02 mmole/g when 12 g of monochloroacetic acid is added. Therefore, it is important to control pulp fiber characteristics to achieve the desired quality of carboxymethyl cellulose.

Keywords
Pulp
carboxymethyl cellulose
fiber length and width
alpha-cellulose
fiber fractionation
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Information
  • Publisher :Korea Technical Association of The Pulp and Paper Industry
  • Publisher(Ko) :한국펄프종이공학회
  • Journal Title :Journal of Korea TAPPI
  • Journal Title(Ko) :펄프종이기술
  • Volume : 54
  • No :4
  • Pages :85-93
  • Received Date : 2022-07-08
  • Revised Date : 2022-08-10
  • Accepted Date : 2022-08-12
  • DOI :https://doi.org/10.7584/JKTAPPI.2022.08.54.4.85
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