柔性TiO2纳米管薄膜电极的制备及其光电性能

doi:10.7517/j.issn.1674-0475.2008.03.224

影像科学与光化学 ›› 2008, Vol. 26 ›› Issue (3): 224-232.DOI: 10.7517/j.issn.1674-0475.2008.03.224

柔性TiO₂纳米管薄膜电极的制备及其光电性能

张凤, 陶杰, 陶海军, 董祥

南京航空航天大学, 材料科学与技术学院, 江苏, 南京210016

收稿日期:2007-07-29 修回日期:2007-11-05 出版日期:2008-05-23 发布日期:2008-05-23
通讯作者: 陶杰(1963- ),男,教授,博士生导师,主要研究方向为金属表面功能涂层和染料敏化太阳能电池,通讯联系人,Tel:025-52112900,E-mail:taojie@nuaa.edu.cn
基金资助:
江苏省自然科学基金(BK2004129);江苏省高校科研成果产业推进工程项目(JHB06-03)

Preparation and Photoelectric Performance of Flexible Titania Nanotubes Thin Film

ZHANG Feng, TAO Jie, TAO Hai-jun, DONG Xiang

College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, Jiangsu, P. R. China

Received:2007-07-29 Revised:2007-11-05 Online:2008-05-23 Published:2008-05-23

摘要/Abstract

摘要： 采用水热合成法制备出TiO₂纳米管,通过XRD、TEM和氮气等温吸附-脱附仪等测试手段对TiO₂纳米管进行了表征.用烧结的TiO₂纳米管和P25粉末混合制成薄膜电极,并研究了薄膜电极的表面形貌、染料吸附量和光电性能.研究表明,加入TiO₂纳米管可以制备出机械稳定的薄膜;掺杂TiO₂纳米管的含量越多,薄膜电极的染料吸附量越大;掺杂5%烧结纳米管粉末的薄膜电极的光电性能最好,其短路电流可达3.25mA,光电转换效率达到1.67%.

关键词: TiO₂纳米管, 水热法, TiO₂薄膜电极, 柔性染料敏化太阳能电池, 光电性能

Abstract: The titania nanotubes were synthesized by hydrothermal process. TiO₂ nanotubes were characterized by means of TEM, XRD and nitrogen adsorption-desorption isotherms. The TiO₂ thin film electrodes were prepared by the titania nanotubes and P25, the surface morphologies, dye loading and photoelectric performance of the film electrodes were analyzed. It is found that the film electrodes are mechanical stable with the addition of the titania nanotubes, The more titania nanotubes film electrodes contain, the higher dye they absorb. When the content of titania nanotubes is 5%, the best photoelectric performance of the film electrodes can be achieved. Its short circuit current of flexible DSSC is 3.25 mA with 1.67% solar-to-electric energy conversion efficiency.

Key words: titania nanotubes, hydrothermal method, TiO₂ thin film electrode, flexible DSSC, photoelectric performances

中图分类号:

O646

张凤, 陶杰, 陶海军, 董祥. 柔性TiO₂纳米管薄膜电极的制备及其光电性能[J]. 影像科学与光化学, 2008, 26(3): 224-232.

ZHANG Feng, TAO Jie, TAO Hai-jun, DONG Xiang. Preparation and Photoelectric Performance of Flexible Titania Nanotubes Thin Film[J]. Imaging Science and Photochemistry, 2008, 26(3): 224-232.

参考文献

[1] O'Regan B,Gratzel M.A low-cost high-efficiency solar cell based on dye-sensitized colloidal TiO₂ films[J].Nature,1991,353:737-740.
[2] 葛伟杰,周保学,张哲,等.染料敏化太阳能电池纳米TiO₂制备及多孔电极膜研究进展[J].环境化学,2005,24(6):726-730.Ge W J,Zhou BX,Zhang Z,et al.Developments in the studies of nano-TiO₂ and mesoporous membrane of dye-sensitized solar cells[J].Environmental Chemistry,2005,24(6):726-730.
[3] Lee K M,Suryanamyanan V,Ho K C.The influence of surface morphology of TiO₂ coating on the performance of dye-sensitized solar cells[J].Sol.Energy Mater.Sol.Cells,2006,90:2398-2404.
[4] Zhang X T,Sutanto I,Taguchi T,et al.Al₂O₃-coated nanoporous TiO₂ electrode for solid-state dye-sensitized solar cell[J].Sol.Energy Mater.Sol.Cells,2003,80:315-326.
[5] Singh R S,Rangari V K,Sanagapalli S,et al.Nano-structured CdTe,CdS and TiO₂ for thin film solar cell applications[J].Sol.Energy Mater.Sol.Cells,2004,82:315-330.
[6] Yu P,Zhu K,Norman A G,et al.Nanocrystalline TiO₂ solar cells sensitized with InAs quantum dots[J].J.Phys.Chem.B,2006,110:25451-25454.
[7] Jiu J T,Wang F M,Adachi M,et al.Highly efficient dye-sensitized solar cells based on single crystalline TiO₂ nanorod film[J].Chem Lett,2005,34(11):1506-1507.
[8] Tan B,Wu Y Y.Dye-sensitized solar cells based on anatase TiO₂ nanoparticle/nanowire composites[J].J.Phys.Chem.B,2006,110:15932-15938.
[9] 马玉涛,林原,肖绪瑞,等.TiO₂纳米管薄膜的制备及其光散射性能[J].科学通报,2005,50(17):1824-1828.Ma Y T,Lin Y,Xiao X R,et al.Titania nanotubes thin film and its light-scattering properties[J].Chinese Science Bulletin,2005,50(17):1824-1828.
[10] 马廷丽.新型有机太阳电池塑料薄膜化的研究进展[J].化学进展,2006,18(2-3):176-181.Ma T L.Progress in a new type of plastic organic solar cell[J].Progress in Chemistry,2006,18(2-3):176-181.
[11] Zbang D S,Yoshida T,Furuta K.Hydrothermal preparation of porous nano-crystalline TiO₂ electrodes for flexible solar cells[J].J Photochem and Photobio A:Chemistry,2004,164:159-166.
[12] 李成玉,林原,李学萍,等.热液法低温制备纳晶TiO₂多孔薄膜电极[J].科学通报,2005,50(6):527-530.Li C Y,Lin Y,Li X P,et al.Nanocrystalline TiO₂ thin film electrodes prepared by common pressure hydrothermal method at low temperature[J].Chinese Science Bulletin,2005,50(6):527-530.
[13] Chen Q,Du G H,Zhang S,et al.The structure of trititanate nano-tubes[J].Acta Cryst.,2002,B58:587-593.
[14] 孙世国,徐勇前,时磊.纳米晶体太阳能电池及染料敏化剂[J].染料与染色,2003,40(6):311-313.Sun S G,Xu Y Q,Shi L,et al.Nanocrystalline photovoltaic solar cells and photosensitive dyes[J].Dyestuffs and Coloration,2003,40(6):311-313.
[15] 冯彩霞,金振声,杨建军,等.镶嵌CdS的纳米管钛酸制备及其光催化性能研究[J].感光科学与光化学(影像科学与光化学),2004,22(4):272-276.Feng C X,Jin Z S,Yang J J,et al.Preparation of CdS-inserted nanotubed titanic acid and its photocatalytic property[J].Photographic Science and Photochemistry (Imaging Science and Photochemistry),2004,22(4):272-276.
[16] 冯彩霞,金振声,王小冬,等.镶嵌铂的纳米管钛酸制备及其可见光光催化活性[J].感光科学与光化学(影像科学与光化学),2007,25(1):12-17.Feng C X,Jin Z S,Wang X D,et al.Preparation and photocatalytic behavior of Pt-inserted nanotube titanic acid under visible light irradiation[J].Photographic Science and Photochemistry (Imaging Science and Photochemistry),2007,25(1):12-17.
[17] Graltzel M.Solar energy conversion by dye-sensitized photovoltaic cells[J].Inorg.Chem.,2005,44:6841-6851.
[18] Yanagida S.Recent research progress of dye-sensitized solar cells in Japan[J].C.R.Chimie,2005,1-8.
[19] Ohsaki Y,Masaki N,Kitamura T,et al.Dye-sensitized TiO₂ nanotube solar cells:fabrication and electronic characterization[J].Phys.Chem.Chem.Phys.,2005,7:4157-4163.
[20] Nazeruddin M K,Kay A,Radicio I,et al.Conversion of light to electricity by cis-X₂ bis (2,2-bipyridyl-4,4-dicarboxy-late) ruthenium (Ⅱ) charge-transfer sensitizers (X=Cl^-,Br^-,I^-,CN^-,and SCN^-) on nanocrystalline TiO₂ electrodes[J].J.Am.Ceram.Soc.,1993,115(14):6382-6390.

柔性TiO₂纳米管薄膜电极的制备及其光电性能

Preparation and Photoelectric Performance of Flexible Titania Nanotubes Thin Film

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