Because the advances of technology, e-learning has been gradually taken seriously. E-learning doesn't limit by time and space, it means that students’ motivation is very important. So how to enhance students’ willingness to learn becomes an important topic. In recent years, the rapid growth of community websites to provide users with various ways to communicate, especially Facebook has more than 10 million registrants in Taiwan. This study wants to enhance students’ motivation through Facebook's high utilization and interaction. In order to achieve the purpose of appropriate learning, both traditional teaching and e-learning should pay attention to students’ personal qualities. According to students’ interests, preferences, and learning methods, give the corresponding teaching methods to enhance students’ learning performance. Therefore, this study will consider students’ learning styles, integrating collaborative learning with Facebook to discuss the impact of learning styles on motivation and learning performance by experiment method. The research findings are following: 1.Students with assimilation learning style had significantly higher score on the dimension “extrinsic goal orientation” of motivation than students with divergence learning style. 2.Integrating collaborative learning with Facebook, learning styles didn’t make a significant difference to motivation and learning performance. 3.Students’ participation was significantly positive related to their learning performance. 4.The dimension “expectancy for success” of motivation was significantly positive related to students’ learning performance.