A Cd(II) complex based on fluconazole and isophthalate ligands, {[Cd(HFlu)(IPA)(H2O)] · H2O}n (1), (HFlu=fluconazole; H2IPA=isophthalic acid) has been synthesized. Single-crystal X-ray analysis reveals that complex 1 has a 2D network structure including unusual triple hydrogen bonds between hydroxyl and triazolyl groups. The complex has also been characterized by IR, UV=Vis and fluorescence spectroscopy, elemental analysis, and thermogravimetry
Graphical Abstract
Synthesis, Structure and Properties of a 2D Cadmium(II) Coordination Polymer Based on Fluconazole and Isophthalate Ligands
Keywords: Triple Hydrogen Bond; Coordination Polymer; Fluconazole; UV=Vis Spectra; Fluorescence; Thermogravimetry
Received: 2013-6-17
Published Online: 2014-6-2
Published in Print: 2013-12-1
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