アリルアルコール等価試薬としてのアリルシラン
1982 年 40 巻 6 号 p. 518-524
詳細
1982 年 40 巻 6 号 p. 518-524
This article describes the regiospecific phenylselenodesilylation of allylsilanes and the synthetic application of allylsilanes as potent synthons of allylic alcohol skeletons. 2- or 3-bromoallyltrimethylsilanes are represented to give the novel reagents for the introduction of allylic alcohol skeletons to several electrophiles by way of formation of allylselenide or allylsulfide and subsequent oxidative rearrangement.
