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HomeSolid State PhenomenaSolid State Phenomena Vol. 290Physical and Structural Properties of Neodymium...

Physical and Structural Properties of Neodymium Doped Lithium Boro-Tellurite Glasses

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Abstract:

Nd³⁺ doped lithium borotellurite glasses were successfully been prepared by conventional melt-quenching method with the chemical composition (70.0)B₂O₃-(5.0)TeO₂-(25.0-x) Li₂CO₃-xNd₂O₃(where x = 0.0, 0.2, 0.4, 0.6, 0.8 and 2.0 mol%) by varying the Neodymium content. The physical properties such as density, molar volume and oxygen packing density were measured. The structural properties have been studied through X-ray diffraction (XRD) analysis and Fourier Transform Infrared (FTIR) spectroscopy. The XRD pattern has been used to confirm the amorphous nature of the glass samples. There are no sharp peaks were observed in XRD patterns of the glass samples which confirmed the amorphous nature of the glass. FTIR spectra were used to analyse the functional groups present in the glass samples. The FTIR spectra reveal the presence of B-O-B, B-O, BO_3,BO₄_,Te-O and characteristic of the hydrogen bond in the prepared glass samples.

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Solid State Science and Technology VI

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Periodical:

Solid State Phenomena (Volume 290)

Pages:

53-59

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.290.53

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Online since:

April 2019

Authors:

Norihan Yahya*, Ahmad Ridzwan Bin Ab Rahim, Mardhiah Abdullah

Keywords:

Lithium Borotellurite Glass, Melt Quenching, Neodymium, Physical Properties, Structural Properties

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[1] Suthanthirakumar, P., Karthikeyan, P., Manimozhi, P. K., and Marimuthu, K. (2015). Structural and spectroscopic behavior of Er3+/Yb3+ co-doped boro-tellurite glasses. Journal of Non-Crystalline Solids, 410, 26-34.

DOI: 10.1016/j.jnoncrysol.2014.12.012

[2] Jha, A. R. (2014). Rare earth materials: properties and applications. CRC Press.

[3] Nurul Ain, A. M., Sahar, M. R., Sazali, E. S., Azman, K., and Norihan, Y. (2017). Study on Optical Absorption and Structural Bonding of Lithium Zinc Phosphate Glasses. In Solid State Phenomena, 268, 54-61.

DOI: 10.4028/www.scientific.net/ssp.268.54

[4] Gedam, R. S., and Ramteke, D. D. (2012). Electrical and optical properties of lithium borate glasses doped with Nd2O3. Journal of rare Earths, 30(8), 785-789.

DOI: 10.1016/s1002-0721(12)60130-6

[5] Azevedo, J., Coelho, J., Hungerford, G., and Hussain, N. S. (2010). Lasing transition (4F3/2→ 4I11/2) at 1.06 μm in neodymium oxide doped lithium boro tellurite glass. Physica B: Condensed Matter, 405(22), 4696-4701.

DOI: 10.1016/j.physb.2010.08.066

[6] Babu, S. S., Rajeswari, R., Jang, K., Jin, C. E., Jang, K. H., Seo, H. J., and Jayasankar, C. K. (2010). Spectroscopic investigations of 1.06 μm emission in Nd3+-doped alkali niobium zinc tellurite glasses. Journal of Luminescence, 130(6), 1021-1025.

DOI: 10.1016/j.jlumin.2010.01.017

[7] Kamitsos, E. I., and Chryssikos, G. D. (1991). Borate glass structure by Raman and infrared spectroscopies. Journal of molecular structure, 247, 1-16.

DOI: 10.1016/0022-2860(91)87058-p

[8] Maheshvaran, K., Linganna, K., and Marimuthu, K. (2011). Composition dependent structural and optical properties of Sm3+ doped boro-tellurite glasses. Journal of Luminescence, 131(12), 2746-2753.

DOI: 10.1016/j.jlumin.2011.06.047

[9] Pawar, P. P., Munishwar, S. R., Gautam, S., and Gedam, R. S. (2017). Physical, thermal, structural and optical properties of Dy3+ doped lithium alumino-borate glasses for bright W-LED. Journal of Luminescence, 183, 79-88.

DOI: 10.1016/j.jlumin.2016.11.027

[10] Mhareb, M. H. A., Hashim, S., Ghoshal, S. K., Alajerami, Y. S. M., Saleh, M. A., Dawaud, R. S., and Azizan, S. A. B. (2014). Impact of Nd3+ ions on physical and optical properties of Lithium Magnesium Borate glass. Optical Materials, 37, 391-397.

DOI: 10.1016/j.optmat.2014.06.033

[11] Gabr, M., Ali, K. A. A., and Mostafa, A. G. E. D. (2007). Infrared Analysis and Physical Properties Studies of B2O3.CaO.ZnO.TiO2 Glass System. Turkish Journal of physics, 31(1), 31-40.

[12] Ratnakaram, Y. C., Babu, S., Bharat, L. K., and Nayak, C. (2016). Fluorescence characteristics of Nd3+ doped multicomponent fluoro-phosphate glasses for potential solid-state laser applications. Journal of Luminescence, 175, 57-66.

DOI: 10.1016/j.jlumin.2016.02.009

[13] Barrow, N. (2006). Superstructural Units in Lithium Borate Glasses. Department of Physics, University of Warwick, Coventry, CV4 7AL.

[14] El-Deen, L. S., Al Salhi, M. S., and Elkholy, M. M. (2008). IR and UV spectral studies for rare earths-doped tellurite glasses. Journal of Alloys and Compounds, 465(1-2), 333-339.

DOI: 10.1016/j.jallcom.2007.10.104

[15] Pascuta, P., Pop, L., Rada, S., Bosca, M., and Culea, E. (2008). The local structure of bismuth borate glasses doped with europium ions evidenced by FT-IR spectroscopy. Journal of Materials Science: Materials in Electronics, 19(5), 424-428.

DOI: 10.1007/s10854-007-9359-5

[16] Madhu, A., Eraiah, B., Manasa, P., and Basavapoornima, C. (2018). Er3+-ions doped lithium-bismuth-boro-phosphate glass for 1532 nm emission and efficient red emission up conversion for telecommunication and lasing applications. Journal of Non-Crystalline Solids, 495, 35-46.

DOI: 10.1016/j.jnoncrysol.2018.04.060