Paper Titles

Synthesis and Characterization of White Mineral Trioxide Aggregate Using Precipitated Calcium Carbonate Extracted from Limestone
p.330

Stainless Steel 316 L Metal Coating with Capiz Shell Hydroxyapatite Using Electrophoretic Deposition Method as Bone Implant Candidate
p.336

Effect of Varying Water-to-Powder Ratios on Compressive Strength and Porosity of Mineral Trioxide Aggregate
p.345

Patch Film from Celullose Derivative Incorporating with Virgin Coconut Oil and its Physical and Antibacterial Properties
p.351

Synthesis of Silver Nanoparticles Using Tyrosine as Reductor and Capping Agent
p.360

Preparation of Chitosan-Polycaprolactone (PCL) Composite Nanofiber as Potential for Annulus Fibrosus Regeneration
p.368

The Influence of SMAT and Polishing on the Degradation of AZ31B Magnesium Alloy in 3.5 Wt.% NaCl Solution
p.377

Effect of Nitro Group on Imidazole Derivative as Colorimetric Chemosensor for Amines
p.385

Simple and Low-Cost Rotating Analyzer Ellipsometer (RAE) for Wavelength Dependent Optical Constant Characterization of Novel Materials
p.392

HomeKey Engineering MaterialsKey Engineering Materials Vol. 840Synthesis of Silver Nanoparticles Using Tyrosine...

Synthesis of Silver Nanoparticles Using Tyrosine as Reductor and Capping Agent

Article Preview

Abstract:

Synthesis and stability of silver nanoparticles (AgNPs) using tyrosine as a reducing and capping agent have been done. Synthesis of AgNPs was performed by mixing silver nitrate (AgNO₃) solution as a precursor with tyrosine amino acid and heating it in a boiling water bath until characterized by the appearance of color change from colorless to yellow. Variations in pH, concentration, and reaction time affecting the formation of AgNPs were studied using UV-Vis spectrophotometry in the wavelength range of 300-700 nm as the main device. The synthesis was successfully conducted at pH 11 for 45 min with the optimum tyrosine concentration was 3 mM for 0.5 mM AgNO₃. The optimum mole ratio AgNO₃ 0.5 mM to tyrosine 3 mM was 1:6. TEM and PSA characterizations showed that the particle was a round shape and 29.5 nm is average size, respectively.

You might also be interested in these eBooks

Symposium of Materials Science and Chemistry II

Info:

Periodical:

Key Engineering Materials (Volume 840)

Pages:

360-367

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.840.360

Citation:

Cite this paper

Online since:

April 2020

Authors:

Desi Indriyani Saragih, Devita Cahyani Varin Arifin, Bambang Rusdiarso, Suyanta Suyanta, Sri Juari Santosa*

Keywords:

Capping Agent, Reducting Agent, Silver Nanoparticles, Tyrosine

Export:

RIS, BibTeX

Price:

Permissions:

Request Permissions

* - Corresponding Author

[1] M. Abdullah, Khaerurijjal, Characterization of nanomaterials: Theory, application, and processing of data, Sustenance Putera, Bandung, (2009).

[2] T. Tsuzuki, Commercial scale production of inorganic nanoparticles, Int. J. Nanotechnol. 6 (2009) 567-578.

[3] M.C. Rodríguez-Argüelles, C. Sieiro, R. Cao, L. Nasi, Chitosan and silver nanoparticles as pudding with raisins with antimicrobial properties, J. Colloid Interf. Sci. 364 (2011) 80-84.

DOI: 10.1016/j.jcis.2011.08.006

[4] S. Iravani, H. Korbekandi, S.V. Mirmohammadi, B. Zolfaghari, Synthesis of silver nanoparticles: chemical, physical and biological methods, Research in Pharmaceutical Sciences 9 (2014) 385-406.

[5] S.A. Al-Thabaiti, F.M. Al-Nowaiser, A.Y. Obaid, A.O. Al-Youbi, Z. Khan, Formation and characterization of surfactant stabilized silver nanoparticles: a kinetic study, Colloid Surf. B Biointerfaces 67 (2008) 230-237.

DOI: 10.1016/j.colsurfb.2008.08.022

[6] R. Yoksan, S. Chirachanchai, Silver nanoparticle-loaded chitosan-starch based films: Fabrication and evaluation of tensile, barrier, and antimicrobial properties, Mat. Sci. Eng. C 30 (2010) 891-897.

DOI: 10.1016/j.msec.2010.04.004

[7] P.R. Selvakannan, A. Swami, D. Srisathiyanarayanan, P.S. Shirude, R. Pasricha, A.B. Mandale, Synthesis of aqueous Au core–Ag shell nanoparticles using tyrosine as a pH-dependent reducing agent and assembling phase-transferred silver nanoparticles at the air-water interface, Langmuir 20 (2004) 7825-7836.

DOI: 10.1021/la049258j

[8] Pelczar, J. Michael, E.C.S. Chan, Fundamentals of Microbiology, University of Indonesia, Jakarta, (2005).

[9] P. Spring, Understanding Development of the Avian Gastrointestinal microflora: an essential key for developing competitive exclusion products, Proc. Alltech 11th Annual Asian Pacific Lecture-Tour, 1997 149-160.

[10] R. Octaviani, Chromatogram profile and antibacterial activity of ethanol extract of zingiber zerumbet on Escherichia coli bacteria in vitro, Thesis, Diponegoro University Medical Faculty, Semarang, (2007).

[11] E. Jawetz, J.L. Melnick, E.A. Adelberg, Medical Microbiology, 20th Ed, EGC, Medical Book Publishers, Jakarta, (1996).

[12] S. Shankar, J.W. Rhim, Amino acid mediated synthesis of silver nanoparticles and preparation of antimicrobial agar/silver nanoparticles composite films, Carbohydr. Polym. 130 (2015) 353-363.

DOI: 10.1016/j.carbpol.2015.05.018

[13] A. Quaranta, S. Carturan, M. Bonafini, G. Maggioni, M. Tonezzer, G. Mattei, C.J. Fernandez, G.D. Mea, P. Mazzoldi, Optical sensing to organic vapors of fluorinated polyimide nanocomposites containing silver nanoclusters, Sens. Actuators B 118 (2006) 418-424.

DOI: 10.1016/j.snb.2006.04.046

[14] G. Gusrizal, Synthesis of silver nanoparticles by reduction of silver ion with 2-,3-, 4- hydroxybenzoic acid and their application for determination of paraquat, Dissertation, Chemistry Study Program, Universitas Gadjah Mada, Yogyakarta, (2017).

[15] M. Stevanonic, I. Savanonic, V. Uskokovic, S.D. Skapin, I. Bracko, U. Javanonic, D. Uskokovic, A new, simple, green, and one-pot four-component synthesis of bare and poly (α,ɤ, L-glutamic acid)-capped silver nanoparticles, Col. Poly. Sci. 290 (2012) 221-231.

DOI: 10.1007/s00396-011-2540-7

[16] K.B. Ali, S. Ahmed, Q. Dwivedi, A. Saquib, Abdulaziz, J. Al Khedhairy, Musarrat, Microwave accelerated green synthesis of stable silver nanoparticles with eucalyptus globulus leaf extract and their antibacterial and anti biofilm activity on clinical isolates, PLoS ONE 1 (2015) 1-20.

DOI: 10.1371/journal.pone.0131178

[17] L. Kvitek, A. Panacek, J. Sukupova, M. Kolar, R. Veceroova, R. Prucek, M. Hlecova, R. Zboril, Effect of surfactants and polymers stability and antibacterial activity of silver nanoparticles (NPs), J. Phys. Chem. C 112 (2008) 5825-5834.

DOI: 10.1021/jp711616v

[18] V.V. Pinto, M.J. Ferreira, R. Silva, H.A. Santos, F. Silva, C.M. Pereira, Long time effect on the stability of silver nanoparticles in aqueous medium: effect of the synthesis and storage conditions, Colloid. Surf. A Physicochem. Eng. Asp. 364 (2010) 19-25.

DOI: 10.1016/j.colsurfa.2010.04.015

[19] M. Tejamaya, I. Romer, R.C., Merrifield, J. R. Lead, Stability of citrate, PVP, and PEG, coated silver nanoparticles in ecoxicology media, Environ. Sci. Technol. 46 (2012) 7011-7017.

DOI: 10.1021/es2038596

[20] I.L. Gunsolus, M.P.S. Mousavi, K. Hussein, P. Bϋhlmann, C. L. Haynes, Effects of humics and fulvic acid on silver nanoparticle stability, dissolution, and toxicity, Environ. Sci. Technol. 45 (2015) 5564-5571.

DOI: 10.1021/acs.est.5b01496

[21] M.G. Guzmán, J. Dille, S. Godet, Synthesis of silver nanoparticles by chemical reduction method and their antibacterial activity, Int. J. Chem. Biol. Eng. 2 (2009) 104-111.

[22] P. Pathak, M. Nagarsenker, Formulation and evaluation of lidocaine lipid nanosystems for dermal delivery, AAPS Pharm. Sci. Tech. 10 (2009) 985-992.

DOI: 10.1208/s12249-009-9287-1

[23] S. Kashanian, A.H. Azandaryani, K. Derakhshandeh, New surface-modified solid lipid nanoparticles using N-glutaryl phosphatidylethanolamine as the outer shell, Int. J. Nanomedicine 6 (2011) 2393-2401.

DOI: 10.2147/ijn.s20849

[24] Z. Li, W. Li, J. Shen, W. Liu, Development of the measurement and analysis system of nanoparticle size distribution, J. Adv. Mater. Res. 121 (2010) 168-171.