Development of Geopolymer Mortar from Metakaolin Blended with Agricultural and Industrial Wastes

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Abstract:

Geopolymer is a greener alternative cement produced from the reaction of pozzolans and strong alkali solutions. Generally, the cement industry is one of largest producers of CO2 that caused global warming. For geopolymer mortar usage, Portland cement is not utilized at all. In this research, geopolymer mortars were prepared by mixing metakaolin, various wastes (fly ash, bagasse ash and rice husk ash) varied as 80:20, 50:50 and 20:80, 15M NaOH, Na2SiO3 and sand. The influence of various parameters such as metakaolin to ashes ratios and pozzolans to alkali ratios on engineering properties of metakaolin blended wastes geopolymer mortar were studied. Compressive strength tests were carried out on 25 x 25 x 25 mm3 cube geopolymer mortar specimens at 7, 14, 21, 28 and 91 air curing days. Physical and chemical properties were also investigated at the same times. The test results revealed that the highest compressive strength was 20% metakaolin - 80% fly ash geopolymer mortar. When the curing times increases, the compressive strength of geopolymer mortar also increases. The mixing of metakaolin and bagasse ash/rice husk ash presented lower compressive strength but higher water absorption and porosity. For FTIR results, Si-O, Al-O and Si-O-Na+ were found. Moreover, the geopolymer mortar could easily plastered on the wall.

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305-310

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April 2018

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[1] Mehta, P. K. 2001. Reducing the environmental impact of concrete. Concrete International 23(10): 61–65.

Google Scholar

[2] Davidovits, j. 1991. Geopolymer: inorganic polymeric new materials. Journal of Thermal Analysis and Calorimetry. 37: 1633–1656.

Google Scholar

[3] Barbosa, V.F.F. and J.D. MacKenzie. 2003. Synthesis and thermal behaviour of potassium sialate geopolymers. Materials Letters 57 (9): 1477–1482.

DOI: 10.1016/s0167-577x(02)01009-1

Google Scholar

[4] Tippayasam, C., S. Boonsalee, S. Sajjavanich, C. Ponzoni , E. Kamseu and D. Chaysuwan.2010. Geopolymer development by powders of metakaolin and wastes in Thailand. Advances in Science and Technology 69:63–8.

DOI: 10.4028/www.scientific.net/ast.69.63

Google Scholar

[5] Li, Z., Z. Ding and Y. Zhang. 2004. Development of sustainable cementitious materials, pp.55-76. In Proceedings of International Workshop on Sustainable Development and Concrete Technology. 20-21 May 2004, Beijing, China.

Google Scholar

[6] Temuujin, J., R.P. Williams and A. van Riessen. 2009. Effect of mechanical activation of fly ash on the properties of geopolymer cured at ambient temperature. Journal of Materials Processing Technology 209: 5276-5280.

DOI: 10.1016/j.jmatprotec.2009.03.016

Google Scholar

[7] Pangdaeng, S., V. Sata, J.B. Aguiar, F. Pacheco and P. Chindaprasirt. 2015. Apatite formation on calcined kaolin-white Portland cement geopolymer. Materials Science and Engineering: C51:1-6.

DOI: 10.1016/j.msec.2015.02.039

Google Scholar