Influence of LDHs on Chloride Ion Binding in Cementitious Materials

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Abstract:

Layered double hydroxides (LDHs) materials could be used in cement and concrete for their ions capturing capacity and to enhance durability of concrete. In this work, properties and chloride binding capacity of different types of LDHs were compared, micro-mechanism of chloride binding of LDHs were analyzed and chloride binding of cement paste incorporating LDHs were investigated. The experimental results show that Mg-Al-NO3 LDHs presents higher chloride ion binding capacity at initial time compared to LDOs calcinated at 500 °C while ion binding capacity of LDHs calms down and LDOs increases with increasing mixing time. Cement paste incorporating LDHs presents higher chloride binding capacity compared with reference sample. All types of LDHs performed beneficial effect on the chloride penetration resistance especially with addition of 1% Mg-Al-NO3 LDOs.

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34-38

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February 2014

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[1] L. Raki, J.J. Beaudoin, L. Mitchell, Layered double hydroxide-like materials: nanocomposites for use in concrete, Cem. Concr. Res. 34(2004) 1717-1724.

DOI: 10.1016/j.cemconres.2004.05.012

Google Scholar

[2] J.N. Enevoldsen, C.M. Hansson, B.B. Hope, Binding of chloride in mortar containing admixed or penetrated chlorides, Cem. Concr. Res. 24 (8) (1994) 1525-1533.

DOI: 10.1016/0008-8846(94)90167-8

Google Scholar

[3] C. Cavani, E. Trfiro, A. Vaccari, Hydrotalcite-type anionic clays: preparation, properties and applications, Catal. Today. 11/2 (1991)173-301.

DOI: 10.1016/0920-5861(91)80068-k

Google Scholar

[4] I.A. Khan, D. Ohare, Intercalation chemistry of layered double hydroxides: recent developments and applications, J. Mater. Chem. 12 (2002) 3191-3198.

DOI: 10.1039/b204076j

Google Scholar

[5] V.R.L. Constantino, T.J. Pinnavaia, Basic properties of Mg2+1-x Al3+x layered double hydroxides intercalated by carbonates, hydroxide, chloride, and sulfate anions, Inorg. Chem. 34 (1995) 883-892.

DOI: 10.1021/ic00108a020

Google Scholar

[6] S.E. Hussain, A. Rasheeduzzafar, A. Al-Musallam, A.S. Al-Gahtani, Factors affecting threshold chloride for reinforcement corrosion in concrete, Cem. Concr. Res. 25 (1995) 1543-1555.

DOI: 10.1016/0008-8846(95)00148-6

Google Scholar

[7] L.T. Mammoliti, L.C. Brown, C.M. Hansson, B.B. Hope, The influence of surface finish of reinforcing steel and pH of the test solution on the chloride threshold concentration for corrosion initiation in synthetic pore solutions, Cem. Concr. Res. 26 (1996).

DOI: 10.1016/0008-8846(96)00018-x

Google Scholar

[8] D. Trejo, R.G. Pillai, Accelerated chloride threshold testing-Part II: corrosion-resistant reinforcement, ACI Mater. J. 101 (2004) 57-64.

DOI: 10.14359/12988

Google Scholar

[9] M. Meyn, K. Beneke, G. Lagaly, Anion-exchange reactions of layered double hydroxides, Inorg. Chem. 29 (1990) 5201-5207.

DOI: 10.1021/ic00351a013

Google Scholar

[10] J. Olanrewaju, B.L. Newalkar, C. Mancino, S. Komrneni, Simplified synthesis of nitrate form of layered double hydroxide, Mater. Lett. 45(2000) 307-310.

DOI: 10.1016/s0167-577x(00)00123-3

Google Scholar