Supramolecular Hydrogen Bonding Interactions of Novel 1,3,5-Benzenetricarbonyl Trisubstituted Alkyl for Anion Sensor Applications

Juan Matmin; Leny Yuliati; Mustaffa Shamsuddin; Hendrik O. Lintang

doi:10.4028/www.scientific.net/AMR.925.228

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 925Supramolecular Hydrogen Bonding Interactions of...

Supramolecular Hydrogen Bonding Interactions of Novel 1,3,5-Benzenetricarbonyl Trisubstituted Alkyl for Anion Sensor Applications

Abstract:

Herein we report the first example of benzene-1,3,5-tricarboxamide bearing hydrophobic aminododecane side chains (1) which spontaneously forms supramolecular network by a hydrogen bonding interaction. The compound 1 was synthesized by Schotten-Baumann reaction of 1,3,5-benzenetricarbonyl trichloride and 1-aminododecane in the presence of N,N-diisopropylethylamine. Nuclear Magnetic Resonance (NMR), Mass Spectrometry (MS), and Fourier Transform Infrared (FTIR) spectroscopies have proved the successful synthesis of 1 in 93% as white powder solid. The supramolecular organization was successfully utilized for sensing of nitrate anions by deformation of the hydrogen bonding to form inactive nitroso groups.

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Periodical:

Advanced Materials Research (Volume 925)

Pages:

228-232

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.925.228

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Online since:

April 2014

Authors:

Juan Matmin, Leny Yuliati, Mustaffa Shamsuddin, Hendrik O. Lintang*

Keywords:

Anion Sensors, Benzene Tricarboxamide, Hydrogen Bonding, Self-Assembly, Supramolecules

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