Analytical Fast Pyrolysis of Glucose, Cellubiose and Cellulose: Comparison of the Pyrolytic Product Distribution

Hang Tao Liao; Yang Zhang; Qiang Lu; Chang Qing Dong

doi:10.4028/www.scientific.net/AMR.805-806.186

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 805-806Analytical Fast Pyrolysis of Glucose, Cellubiose...

Analytical Fast Pyrolysis of Glucose, Cellubiose and Cellulose: Comparison of the Pyrolytic Product Distribution

Abstract:

Analytical pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) was employed for the fast pyrolysis of glucose, cellubiose and cellulose in this study. The pyrolytic products from the three glucose-based materials were determined and compared to reveal the distribution differences. The results indicated that fast pyrolysis of the three materials obtained similar pyrolytic products, including the anhydrosugars, furans, linear carbonyls and cyclopentanones, but the distribution of the pyrolytic products differed from each other. The cellulose formed more anhydrosugars, but less carbonyls and furans than the glucose and cellubiose. The glycosidic bond of the cellubiose and cellulose would favor the pyrolytic depolymerization reactions to form various anhydrosugars, while inhibit the pyrolytic fragmentation reactions to produce linear carbonyls.

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Periodical:

Advanced Materials Research (Volumes 805-806)

Pages:

186-190

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.805-806.186

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Online since:

September 2013

Authors:

Hang Tao Liao, Yang Zhang, Qiang Lu, Chang Qing Dong

Keywords:

Cellubiose, Cellulose, Fast Pyrolysis, Glucose, Production Distribution, Py-GC/MS

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References

[1] A.V. Bridgwater and G.V.C. Peacocke: Renew. Sust. Energ. Rev. Vol. 4(1) (2000), p.1.

Google Scholar

[2] D. Mohan, C.U. Pittman and P.H. Steele: Energ Fuel Vol. 20 (2006), p.848.

Google Scholar

[3] R.H. Venderbosch and W. Prins: Biofuel Bioprod. Bioresour. Vol. 4 (2010), p.178.

Google Scholar

[4] S. Czernik and A.V. Bridgwater: Energ Fuel Vol. 18(2) (2004), p.590.

Google Scholar

[5] Q. Lu, W.Z. Li and X.F. Zhu: Energ Convers. Manage. Vol. 50 (2009), p.1376.

Google Scholar

[6] F. Shafizadeh and Y.L. Fu: Carbohydr. Res. Vol. 29 (1973), p.113.

Google Scholar

[7] A.D. Pouwels, G.B. Eijkel and J.J. Boon: J. Anal. Appl. Pyrol. Vol. 14 (1989), p.237.

Google Scholar

[8] R. Alen, E. Kuoppala and P. Oesch: J. Anal. Appl. Pyrol. Vol. 36 (1996), p.137.

Google Scholar

[9] D. Fabbri, S. Prati, I. Vassura and G. Chiavari: J. Anal. Appl. Pyrol. Vol. 68–69 (2003), p.163.

Google Scholar

[10] D.K. Shen, S. Gu and A.V. Bridgwater: Carbohydr. Polym. Vol. 82 (2010), p.39.

Google Scholar

[11] D. Fabbri, C. Torri and V. Baravelli: J. Anal. Appl. Pyrol. Vol. 80 (2007), p.24.

Google Scholar

[12] G. R Ponder, G. N Richards and T. T Stevenson: J. Anal. Appl. Pyrol. Vol. 22 (1992), p.217.

Google Scholar