Synthesis of Pyrrolidine Substituted Perylene Imide End Capped with POSS Nanoparticle and a Preliminary Study of its Electronic Properties

Lodrick Makokha Wangatia; Ting Zeng; Bin Sun; Mei Fang Zhu

doi:10.4028/www.scientific.net/AMR.668.701

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 668Synthesis of Pyrrolidine Substituted Perylene...

Synthesis of Pyrrolidine Substituted Perylene Imide End Capped with POSS Nanoparticle and a Preliminary Study of its Electronic Properties

Abstract:

Nanoparticle amino polyhedral oligomeric silsesquioxanes (POSS) substituted at the end core of 1,7 bay amino substituted perylene imide dye (POSS-PDIpy) and characterized using FT-IR and NMR. Concentration dependant UV-Vis absorption showed reduction in aggregation due to double suppression of π-π interaction by pyrrolidine and POSS substitution. Bay substitution of the PDI with pyrrolidine red shifted the maximum absorption peak to near infrared region which is a good condition for maximum light absorption, this may have good potential for use in optoelectronic application.

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Periodical:

Advanced Materials Research (Volume 668)

Pages:

701-705

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.668.701

Citation:

Cite this paper

Online since:

March 2013

Authors:

Lodrick Makokha Wangatia, Ting Zeng, Bin Sun, Mei Fang Zhu

Keywords:

Aggregation, Perylene Diimide, Solubility

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