Cs-P Oxide Catalysts for Aldol Condensation to Produce Methyl Acrylate

Shi Feng Jiang; Zhen Qiu Li; Hong Nan Chen; Er Qiang Wang

doi:10.4028/www.scientific.net/AMR.1104.51

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 1104Cs-P Oxide Catalysts for Aldol Condensation to...

Cs-P Oxide Catalysts for Aldol Condensation to Produce Methyl Acrylate

Abstract:

In this research, methyl acrylate has been synthesized from industrial raw material methyl acetate through highly efficient and eco-friendly method, One-step aldol condensation, using acid-base bifunctional catalyst Cs, P and K as catalysts. Carbon deposits and other issues led to the catalysts deactivation in the process of fixed bed, which led to the production interruption. While, the process of circulating fluidized bed can overcome this defect and the catalyst can maintain good catalytic activity in the whole process. Cs (8%), P (5%), K (2%)/γ-Al₂O₃/ catalyst showed better performance due to its high surface area and more weak basicity and acidity. In addition, theoretical calculations and cold model experiments were also conducted in this work to determine the catalyst particle size，operation gas velocity and gas distributor plate.

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Periodical:

Advanced Materials Research (Volume 1104)

Pages:

51-56

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1104.51

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Online since:

May 2015

Authors:

Shi Feng Jiang, Zhen Qiu Li, Hong Nan Chen, Er Qiang Wang

Keywords:

Circulating Fluidized Bed, Cold Model Experiments, Methyl Acrylate, Operation Gas Velocity, Theoretical Calculations

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