A New Method for Synthesis of Iron Phthalocyanine

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Abstract:

Iron phthalocyanine was prepared by the reaction of phthalic anhydride, urea and ferrous chloride by means of the solvent method with dioctyl phthalate as solvent, ammonium molybdenate as a catalyst and ammonium chloride as promoter. The reaction was carried out in the conditions that 2 hours was required for the first stage at the temperature of ca. 403 K and 6 hours was required for the second stage at the temperature of ca. 453 K. The yield of the product reached of 77%. Along with the use of dioctyl phthalate as solvent for the reaction for producing iron phthalocyanine, the whole production process could become more friendly to the environment compared with the traditional methods with trichlorobenzene, nitrobenzene or other substances as the solvent.

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Advanced Materials Research (Volumes 1033-1034)

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3-6

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October 2014

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