Study on Eu Doped ZnO Photocatalytic Degradation of Pharmaceutical Wastewater

Article Preview

Abstract:

In this paper,europium doped zinc oxide nanoparticles were prepared by Zn (CH3COO)2, Eu (NO3)5·6H20,NaOH,PEG2000 and Citric acid using hydrothermal method. The prepared powder was used for photocatalytic degradation, in which the influence ofreaction temperature, reaction time, illumination conditions as well as the doping ratio on the effect of photocatalytic oxidation were throughly investigated. Analytical methods, such as XRD, SEM and EDS were utilized in this study for characterization of the prepared powder. Results showed that Europium-doped zinc oxide with a 3% doping ratio reached optimal photocatalytic oxidation effect when the hydrothermal temperature was 160°C and hydrothermal time was 6 hours. By utilizing the prepared powder under optimal conditions, the decolorization rate of pharmaceutical wastewater reached 38.8% after treatment of 365nm UV irraditation for 150min, and the degradation rate of COD reached 57.5%.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

482-486

Citation:

Online since:

December 2014

Export:

Price:

* - Corresponding Author

[1] Hariharan C. Photocatalytic degradation of organic contaminants in water by ZnO nano-particles: Revisited. Applied Catalysis A: General, 2006, 304(1): 55−61.

DOI: 10.1016/j.apcata.2006.02.020

Google Scholar

[2] Kaneco S, Katsumata H, Suzuki T. etal. Solar photocatalytic degradation of endocrine disruptor dinbuty phthalate in aqueous solution using zinc oxide. Bulletin of the Catalysis Society of India, 2007, 6(3): 22−33.

Google Scholar

[3] Linli Ouyang, Qi Xiao, Zhijian Wang, etc. Zinc Oxide cobalt doped nano material preparation, characterization andcatalytic properties of visible light. Hunan nonferrous metals, 2010, 26(4): 39-42.

Google Scholar

[4] M. Alvaro,B. Cojocaru A.A. Ismail etal. Visible-light photocatalytic activity of gold nanoparticles supported on template-synthesized mesoporous titania for the decontamination of the chemical warfare agent SOMAN. Applied Catalysis B-Environmental, 2010, 99(1): 191–197.

DOI: 10.1016/j.apcatb.2010.06.019

Google Scholar

[5] S. Ekambaram,Y. Iikubo,A. Kudo. Combustion. Synthesis and photocatalytic properties of transition metal-incorporated ZnO. Journal of Alloys and Compounds, 2007, 433(1- 2): 237- 240.

DOI: 10.1016/j.jallcom.2006.06.045

Google Scholar

[6] Xinyong Tao, Xiaobin Zhang, Etc. Hydrothermal synthesis of PEG auxiliary Zinc Oxidenanorods prepared. Journal of Chemical Engineering , 2004, 62(17): 1658-1662.

Google Scholar

[7] Lei Zhu, Yangfan Xiao, Xun Wang. Experimental study on treatment of pharmaceutical wastewater of lanthanum, cerium doped ZnO-TiO2. Environmental Engineering , 2014, 32(2): 6-9.

Google Scholar

[8] Linqing Huang, Jing Huang, Enjuan Zhang, etc. Study and preparation of nano Zinc Oxide for UVabsorption characteristics. China pharmaceutical , 2010, 20(6): 54-55.

Google Scholar

[9] Su Su, Shixiang Xiang, Wenguo Xu. Aluminum doped ZnO nanoparticles photocatalytic degradation of reactivebrilliant blue X- BR. Journal of process engineering, 2008, 8(1): 54- 59.

Google Scholar