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Paper Titles
Preface
Synthesis of TiO2 Nanofiber as Photoanode of Dye Sensitized Solar Cells (DSSC)
p.3
Biopolymer Kappa Carrageenan with Ammonium Chloride as Electrolyte for Potential Application in Organic Battery
p.11
NaFePO4 Particles as a Cathode of Sodium Ion-Battery via Sol-Gel Method: A Review on Synthesis
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Performance Improvement of Dye-Sensitized Solar Cells Using a Combination of TiO2 and ZnO as Photoanodes
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A Rapid Synthesis of Zeolitic Imidazolate Framework-14 Cobalt (ZIF-14 Co) for Surface Modification of LiFePO4 as Lithium‑Ion Battery Cathode Material
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Ferrofluid Mn0.5Zn0.5Fe2O4 as Harvesting Energy: Preliminary Study
p.39
Photovoltaic Characteristics of the a-C/a-C:B Homojunction from Palmyra Sugar with Nano-Spray Method
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Characterization and Performance Evaluation of Yttria-Stabilized Zirconia (YSZ) Thickness on ZnO Nanorods-Based Photoelectrochemical Cell
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Biopolymer Kappa Carrageenan with Ammonium Chloride as Electrolyte for Potential Application in Organic Battery

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Abstract:

Carrageenan is a generic name for a family of natural, water-soluble, sulphated galactans isolated from red seaweeds and exploited commercially. The biopolymer of kappa carrageenan has been known to be used as electrolyte in electrochemical device since it shows good ionic conductivity characteristic. In this study, we attempt to study the chemical, morphology, and electric properties of biopolymer kappa carrageenan. We developed a free-standing film of kappa carrageenan with addition of ammonium chloride as an electrolyte for an organic battery prototype. We prepared the solution by mixing kappa carrageenan, ammonium chloride and water to form a gel with a particular concentration. Then, the gel was coated on the substrate and cured at 50°C for 4 hours. The final free-standing film product reveals a thickness about 100-200 mm as captured by SEM image in cross-section view. The morphology of kappa carrageenan with or without ammonium chloride clearly shows a non-homogeneous surface that attributed to the nature characteristics of kappa carrageenan immiscible. The addition of ammonium chloride into kappa carrageenan forms a smoother surface that show good mixture of kappa carrageenan. FTIR spectra of the samples show the interaction of ammonium chloride to the host polymer of kappa carrageenan as indicated by the shifted of the O-H peak from 3448 to 3446 cm-1 and from 3288 to 3207 cm-1 while the peak of 2924 cm-1 is disappeared after addition of the ammonium chloride. The implementation of this film in an organic C_Zn battery prototype shows that battery’s voltage reached 2.1 Volt by charging. Then, the battery can be used to emit an LED with 20 µA electrical current for about 1 hour in discharging process.

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Info:

Periodical:

Key Engineering Materials (Volume 950)

Pages:

11-16

DOI:

https://doi.org/10.4028/p-FW7xiu

Citation:

Cite this paper

Online since:

July 2023

Authors:

Paula Santi Rudati, Yumna Dzakiyyah, Richie Fane, Maria Artha Febriyanti Turnip, Muhammad Tegar Pambudi, Priastuti Wulandari*

Keywords:

Battery, Electrolyte, Free-Standing Film, Kappa Carrageenan

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* - Corresponding Author

References

[1] P. Christopher Selvin, P. Perumal, S. Selvasekarapandian, S. Monisha, G. Boopathi, and M. V. Leena Chandra, Study of proton-conducting polymer electrolyte based on K-carrageenan and NH4SCN for electrochemical devices, Ionics (Kiel). 24 (2018) 3535–3542.

DOI: 10.1007/s11581-018-2521-7

Google Scholar

[2] V. Moniha, M. Alagar, S. Selvasekarapandian, B. Sundaresan, and R. Hemalatha, Development and Characterization of Bio-Polymer Electrolyte iota-carrageenan with Ammonium Salt for, Mater Today Proc. 8 (2019) 449–455.

DOI: 10.1016/j.matpr.2019.02.135

Google Scholar

[3] E. Armelin, M. M. Pérez-Madrigal, C. Alemán, and D. D. Díaz, Current status and challenges of biohydrogels for applications as supercapacitors and secondary batteries, J Mater Chem A Mater. 4 (2016) 8952–8968.

DOI: 10.1039/c6ta01846g

Google Scholar

[4] J. W. Y. Liew, K. S. Loh, A. Ahmad, K. L. Lim, and W. R. Wan Daud, Synthesis and characterization of modified κ-carrageenan for enhanced proton conductivity as polymer electrolyte membrane, PLoS One. 12 (2017) e0185313.

DOI: 10.1371/journal.pone.0185313

Google Scholar

[5] F. G. Torres and G. E. De-la-Torre, Algal-based polysaccharides as polymer electrolytes in modern electrochemical energy conversion and storage systems: A review, Carbohydrate Polymer Technologies and Applications. 2 (2021) 100023.

DOI: 10.1016/j.carpta.2020.100023

Google Scholar

[6] Y. Huang et al., Flexible quasi-solid-state zinc ion batteries enabled by highly conductive carrageenan bio-polymer electrolyte, RSC Adv. 9 (2019) 16313–16319.

DOI: 10.1039/c9ra01120j

Google Scholar

[7] E. Brands, Eveready Carbon Zinc Battery Handbook and Application Manual, Energizer Brands, LLC, 2018. Information on https://www.energizer.com/.

Google Scholar

[8] J. F. Du, Y. Bai, W. Y. Chu, and L. J. Qiao, Synthesis and performance of proton conducting chitosan/NH 4 Cl electrolyte, J Polym Sci B Polym Phys. 48 (2010) 260–266.

DOI: 10.1002/polb.21866

Google Scholar

[9] B.-A. Mei, O. Munteshari, J. Lau, B. Dunn, and L. Pilon, Physical Interpretations of Nyquist Plots for EDLC Electrodes and Devices, The Journal of Physical Chemistry C. 122 (2018) 194–206.

DOI: 10.1021/acs.jpcc.7b10582

Google Scholar

[10] M. Rayung et al., Bio-Based Polymer Electrolytes for Electrochemical Devices: Insight into the Ionic Conductivity Performance, Materials. 13 (2020) 838.

DOI: 10.3390/ma13040838

Google Scholar

[11] S. Rudhziah, A. Ahmad, I. Ahmad, and N. S. Mohamed, Biopolymer electrolytes based on blend of kappa-carrageenan and cellulose derivatives for potential application in dye sensitized solar cell, Electrochim Acta. 175 (2015) 162–168.

DOI: 10.1016/j.electacta.2015.02.153

Google Scholar

[12] N. N. Mobarak, N. Ramli, A. Ahmad, and M. Y. A. Rahman, Chemical interaction and conductivity of carboxymethyl κ-carrageenan based green polymer electrolyte, Solid State Ion. 224 (2012) 51–57.

DOI: 10.1016/j.ssi.2012.07.010

Google Scholar

[13] S. Rudhziah, N. A. C. Apandi, R. H. Y. Subban, and N. S. Mohamed, Ionic Conductivity of Biopolymer Electrolytes Based on Seaweed kappa-carrageenan, Science Letters. 12 (2018) 45–52.

Google Scholar

[14] R. L. Zornitta, L. A. M. Ruotolo, and L. C. P. M. de Smet, High-Performance Carbon Electrodes Modified with Polyaniline for Stable and Selective Anion Separation, Sep Purif Technol. 290 (2022) 1–10.

DOI: 10.1016/j.seppur.2022.120807

Google Scholar

[15] Y. Liang and Y. Yao, Positioning Organic Electrode Materials in the Battery Landscape, Joule. 2 (2018) 1690–1706.

DOI: 10.1016/j.joule.2018.07.008

Google Scholar

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