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β-双酮三苯基膦混配铜（I）配合物的合成、晶体结构及荧光性质

陈士昆1,2,赵祥华1,吴杰颍1,田玉鹏1*   

  1. (1.安徽大学化学与化工学院 合肥 230039；2.淮南师范学院化学与化工系 淮南)
  • 收稿日期:2011-05-10 修回日期:2011-07-13 出版日期:2012-03-10 发布日期:2012-03-10
  • 通讯作者: 田玉鹏，教授; Tel:0551-5108151; Fax:0551-5107342; E-mail:yptian@ahu.edu.cn; 研究方向：功能配合物
  • 基金资助:
    国家自然科学基金(21071001)资助项目，安徽省教育厅自然科学基金重点项目（KJ2010A030）

Synthesis, Crystal Structure and Fluorescent Property of β-diketone and Triphenylphosphine Copper(I) Mixed-Ligand Complex

CHEN Shikun1,2, ZHAO Xianghua1, WU Jieying1, TIAN Yupeng1*   

  1. (1.Faculty of Chemistry and Chemical Engineering,Anhui University,Hefei 230039;
    2.Department of Chemistry and Chemical Engineering,Huainan Normal University,Huainan)
  • Received:2011-05-10 Revised:2011-07-13 Published:2012-03-10 Online:2012-03-10

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摘要： 按文献方法合成了9-丁基-3-（4，4,4-三氟-1，3-丁二酮基）咔唑（L），以L和三苯基膦为配体与硝酸铜、铜粉反应制备了具有荧光活性的铜(Ⅰ)配合物。 利用红外光谱和元素分析表征了配合物的组成。 通过单晶X射线衍射分析确定了该配合物的晶体结构，晶体属于单斜晶系，P21/c空间群。 晶胞参数：a=1.642 8(5) nm,b=1.043 4(5) nm,c=2.800 1(5) nm，V=4.800(3) nm3，Z=4，Dc=1.313 Mg/m3，R[I＞2σ(I)],R1=0.050 1,wR2=0.080 8。该配合物的分子中，β-二酮配体L的2个O原子和三苯基膦配体的P原子参与配位，Cu(Ⅰ)处于畸变四面体配位中心。 初步研究了Cu(Ⅰ)配合物的发光性质，配合物在二氯甲烷溶液中有很强的荧光发射。

关键词: 丁基-(三氟丁二酮基) 咔唑, 晶体结构

Abstract: A β-diketone ligand L (3-(4,4,4-trifluorobutane-1,3-diketone)-9-butylcarbazole) was synthesized according to literature method. The copper(Ⅰ) complex with fluorescent activity was prepared by the reaction of copper nitrate, copper, triphenylphosphine and L, which was characterized by elemental analysis and IR spectra. Its crystal structure was determined by single crystal X-ray diffraction analysis. The crystal belongs to monoclinic, P21/c space group. Cell parameters:a=1.6428(5) nm, b=1.0434(5) nm, c=2.8001(5) nm, V=4.800(3) nm3, Z=4, Dc=1.313 Mg/m3, R[I＞2σ(I)] R1=0.0501, wR2=0.0808. The Cu(Ⅰ) ion in the distorted tetrahedral copper(Ⅰ) complex is coordinated by two O atoms from the two β-diketone ligands, and two P atoms from triphenylphosphine, respectively. Fluorescent properties of the copper(]Ⅰ) complex were studied, which indicated that the complex had strong fluorescent emission in dichloromethane solution.

Key words: (trifluorobutane diketone)butylcarbazole, Catalytic activity

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