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Decolorization of Reactive Black 5 Using N-Doped TiO2

Year 2022, Volume: 35 Issue: 2, 360 - 370, 01.06.2022

Aslı Berktaş Özlem Esen Kartal

https://doi.org/10.35378/gujs.828761
Cited By: 1

Abstract

Decolorization of Reactive Black 5 (RB5) was investigated by heterogeneous photocatalysis using N-doped TiO2. N-doped TiO2 photocatalysts were synthesized by means of a sol-gel process. X-ray diffraction performed the characterization of synthesized samples, scanning electron microscopy and X-ray photoelectron spectroscopy measurements. Photocatalytic activity of N-doped TiO2 samples was assessed by following decolorization and degradation efficiency of RB5. N-TiO2(3) sample yielded the highest decolorization efficiency. The apparent first-order rate constants for decolorization of RB5 with N-TiO2(X) samples followed the order of N-TiO2(3) > N-TiO2(2) > N-TiO2(4) > N-TiO2(1). Improvement of decolorization efficiency of TiO2 was observed doping with nitrogen. The effect of actual sunlight on decolorization efficiency was also investigated. 96% and 49% of decolorization efficiency levels were attained within 60 minutes of reaction time with outdoor sunlight and fluorescent daylight lamps, respectively. 

Keywords

Sol-gel Nitrogen doping Photocatalysis Reactive Black 5 Solar light

Supporting Institution

Scientific and Technological Research Council of Turkey

Project Number

2209/A

References

  • [1] Holkar, C. R., Jadhav, A. J., Pinjari, D. V., Mahamuni, N.M., Pandit, A.B., “A critical review on textile wastewater treatments: Possible approaches”, Journal of Environmental Management, 182: 351-366, (2016).
  • [2] Rodriguez-Narvaez, O.M., Peralta-Hernandez, J.M., Goonetilleke, A., Bandala, E.R., “Treatment technologies for emerging contaminants in water: A review”, Chemical Engineering Journal, 323: 361-380, (2017). [3] Shahidi, D., Roy, R., Azzouz, A., “Advances in catalytic oxidation of organic pollutants – Prospects for thorough mineralization by natural clay catalysts”, Applied Catalysis B-Environmental, 174-175: 277-292, (2015).
  • [4] Al-Mamun, M.R., Kader, S., Islam, M.S., Khan, M.Z.H., “Photocatalytic activity improvement and application of UV-TiO2 photocatalysis in textile wastewater treatment: A review”, Journal of Environmental Chemical Engineering, 7: 103248, (2019).
  • [5] Wetchakuna, K., Wetchakunb, N., Sakulsermsuk, S., “An overview of solar/visible light-driven heterogeneous photocatalysis for water purification: TiO2 - and ZnO-based photocatalysts used in suspension photoreactors”, Journal of Industrial and Engineering Chemistry, 71: 19-49, (2019).
  • [6] He, X., Wang, A., Wu, P., Tang, S., Zhang, Y., Li, L., Ding, P.,“ Photocatalytic degradation of microcystin-LR by modified TiO2 photocatalysis: A review”, Science of The Total Environment, 743: 140694, (2020).
  • [7] Perillo, P.M., Rodríguez, D.F., “Photocatalysis of Methyl Orange using free standing TiO2 nanotubes under solar light”, Environmental Nanotechnology, Monitoring & Management, 16: 100479, (2021). [8] Asahi, R., Morikawa, T., Ohwaki, T., Aoki, K., Taga, Y., “Visible-light photocatalysis in nitrogen-doped titanium oxides”, Science, 293: 269-271, (2001).
  • [9] Cheng, X., Yu, X., Xing, Z., “Characterization and mechanism analysis of N doped TiO2 with visible light response and its enhanced visible activity”, Applied Surface Science, 258(7): 3244-3248, (2012).
  • [10] Fu, J., Tian, Y., Chang, B., Xi, F., Dong, X., “Facile fabrication of N-doped TiO2 nanocatalyst with superior performance under visible light irradiation”, Journal of Solid State Chemistry, 199: 280-286, (2013). [11] Ansari, S.A., Khan, M.M., Ansari, M. O., Cho, M.H., “Nitrogen-doped titanium dioxide (N-doped TiO2) for visible light photocatalysis”, New Journal of Chemistry, 40: 3000-3009, (2016).
  • [12] Tian, G., Pan, K., Fu, H., Jing, L., Zhou, W., “Enhanced photocatalytic activity of S-doped TiO2-ZrO2 nanoparticles under visible-light irradiation”, Journal of Hazardous Materials, 166: 939-944, (2009).
  • [13] McManamon, C., O’Connell, J., Delaney, P., Rasappa, S., Holmes, J. D., Morris, M. A., “A facile route to synthesis of S-doped TiO2 nanoparticles for photocatalytic activity”, Journal of Molecular Catalysis A: Chemical, 406: 51-57, (2015).
  • [14] Lin, Y.-T., Weng, C.-H., Lin, Y.-H., Shiesh, C., Chen, F.-Y., “Effect of C content and calcination temperature on the photocatalytic activity of C-doped TiO2 catalyst”, Separation and Purification Technology, 116: 114-123, (2013). [15] Sullivan, J.J.A., Neville, E.M., Herron, R., Thampi, K. R., Mac Elroy, J.M.D., “Routes to visible light active C-doped TiO2 photocatalysts using carbon atoms from the Ti precursors”, Journal of Photochemistry and Photobiology A: Chemistry, 289: 60-65, (2014).
  • [16] Peng, F., Cai, L., Yu, H., Wang, H., Yang, J., “Synthesis and characterization of substitutional and interstitial nitrogen-doped titanium dioxides with visible light photocatalytic activity”, Journal of Solid State Chemistry, 181: 130-136, (2008).
  • [17] Asghar, A., Raman, A.A.A., Daud, W.M.A.W., “Advanced oxidation processes for in-situ production of hydrogen peroxide/hydroxyl radical for textile wastewater treatment: a review”, Journal of Cleaner Production, 87: 826-838, (2015). [18] Bilinska, L., Gmurek, M., Ledakowicz, S., “Comparison between industrial and simulated textile wastewater treatment by AOPs – Biodegradability, toxicity and cost assessment”, Chemical Engineering Journal, 306: 550-559, (2016).
  • [19] Ambigadevi, J., Kumar, S.P., Vo, D.V. N., Haran, S.H., Raghavan, T.N.S., “Recent developments in photocatalytic remediation of textile effluent using semiconductor based nanostructured catalyst: A review”, Journal of Environmental Chemical Engineering, 9:104881, (2021).
  • [20] Selvaraj, V., Karthikaa, T.S., Mansiya, C., Alagar, M., “An over review on recently developed techniques, mechanisms and intermediate involved in the advanced azo dye degradation for industrial applications”, Journal of Molecular Structure, 1224: 129195, (2021).
  • [21] Rochkind, M., Pasternak, S., Paz, Y., “Using dyes for evaluating photocatalytic properties: A critical review”, Molecules, 20: 88-110, (2015). [22] Akpan, U.G., Hameed, B.H., “Parameters affecting the photocatalytic degradation of dyes using TiO2-based photocatalysts: A review”, Journal of Hazardous Materials, 170: 520-529, (2009). [23] Collazzo, G.C., Foletto, E.L., Jahn, S.L., Villetti, M.A., “Degradation of Direct Black 38 dye under visible light and sunlight irradiation by N-doped anatase TiO2 as photocatalyst”, Journal of Environmental Management, 98: 107-111, (2012). [24] Yeber, M.C., Zamora, T., Álvarez, R., Medina, P., “N-doped titanium dioxide nanoparticles activated under visible light achieve the photocatalytic degradation of textile azo dye remazol brilliant blue R”, Desalination and Water Treatment, 151: 161–166, (2019). [25] Berktaş, A., Kartal, Ö.E., “Synthesis of N-Doped TiO2 by sol-gel method and investigation of its photocatalytic activity”, 11th National Congress on Chemical Engineering, Eskişehir, 174-177, (2014).
  • [26] Spurr, R.A., Myers, H., “Quantitative analysis of anatase-rutile mixtures with an X-Ray Diffractometer”, Analytical Chemistry, 29: 760-762, (1957).
  • [27] Lin, Y. H., Chiu, T. C., Hsueh, H. T., Chu, H., “N-doped TiO2 photo-catalyst for the degradation of 1, 2-dichloroethane under fluorescent light”, Applied Surface Science, 258: 1581-1586, (2011).
  • [28] Huang, W.C., Ting, J.M., “Novel nitrogen-doped anatase TiO2 mesoporous bead photocatalysts for enhanced visible light response”, Ceramics International, 43(13): 9992-9997, (2017).
  • [29] Kalantari, K., Kalbasi, M., Sonrabi, M., Royaee, S.J., “Synthesis and characterization of N-doped TiO2 nanoparticles and their application in photocatalytic oxidation of dibenzothiophene under visible light”, Ceramics International, 42(13): 14834-14842, (2016).
  • [30] Lee, S., Chou, I.S., Lee, D.K., Kim, D.W., Noh, T.H., Kwak, C.H., Park, S., Hong, K.S., Lee, J.-K., Jung, H.S., “Influence of nitrogen chemical states on photocatalytic activities of nitrogen-doped TiO2 nanoparticles under visible light”, Journal of Photochemistry and Photobiology A: Chemistry, 213: 129-135, (2010).
  • [31] Ma, Y., Zhang, J., Tian, B., Chen, F., Wang, L., “Synthesis and characterization of thermally stable Sm, N co-doped TiO2 with highly visible light activity”, Journal of Hazardous Materials, 182: 386-393, (2010).
  • [32] Gai, L., Mei, Q., Duan, X., Jiang, H., Zhou, G., Tian, Y., Lu, X., “Controlled synthesis of nitrogen-doped binary and ternary TiO2 nanostructures with enhanced visible-light catalytic activity”, Journal of Solid State Chemistry, 199: 271-279, (2013).
  • [33] Senthilnathan, J., Philip, L., “Photocatalytic degradation of lindane under UV and visible light using N-doped TiO2”, Chemical Engineering Journal, 161: 83-92, (2010).
  • [34] Din, M.İ., Khalid, R., Najeeb, J., Hussain, Z., “Fundamentals and photocatalysis of methylene blue dye using various nanocatalytic assemblies- a critical review”, Journal of Cleaner Production, 298: 126567, (2021).
  • [35] Damodar, R.A., You, S. J., “Performance of an integrated membrane photocatalytic reactor for the removal of Reactive Black 5”, Separation and Purification Technology, 71: 44-49, (2010).
  • [36] Turkish State Meteorological Service https://www.mgm.gov.tr/kurumici/radyasyon_iller.aspx?il=malatya Access date: 06.05.2021

Year 2022, Volume: 35 Issue: 2, 360 - 370, 01.06.2022

Aslı Berktaş Özlem Esen Kartal

https://doi.org/10.35378/gujs.828761
Cited By: 1

Abstract

Project Number

2209/A

References

  • [1] Holkar, C. R., Jadhav, A. J., Pinjari, D. V., Mahamuni, N.M., Pandit, A.B., “A critical review on textile wastewater treatments: Possible approaches”, Journal of Environmental Management, 182: 351-366, (2016).
  • [2] Rodriguez-Narvaez, O.M., Peralta-Hernandez, J.M., Goonetilleke, A., Bandala, E.R., “Treatment technologies for emerging contaminants in water: A review”, Chemical Engineering Journal, 323: 361-380, (2017). [3] Shahidi, D., Roy, R., Azzouz, A., “Advances in catalytic oxidation of organic pollutants – Prospects for thorough mineralization by natural clay catalysts”, Applied Catalysis B-Environmental, 174-175: 277-292, (2015).
  • [4] Al-Mamun, M.R., Kader, S., Islam, M.S., Khan, M.Z.H., “Photocatalytic activity improvement and application of UV-TiO2 photocatalysis in textile wastewater treatment: A review”, Journal of Environmental Chemical Engineering, 7: 103248, (2019).
  • [5] Wetchakuna, K., Wetchakunb, N., Sakulsermsuk, S., “An overview of solar/visible light-driven heterogeneous photocatalysis for water purification: TiO2 - and ZnO-based photocatalysts used in suspension photoreactors”, Journal of Industrial and Engineering Chemistry, 71: 19-49, (2019).
  • [6] He, X., Wang, A., Wu, P., Tang, S., Zhang, Y., Li, L., Ding, P.,“ Photocatalytic degradation of microcystin-LR by modified TiO2 photocatalysis: A review”, Science of The Total Environment, 743: 140694, (2020).
  • [7] Perillo, P.M., Rodríguez, D.F., “Photocatalysis of Methyl Orange using free standing TiO2 nanotubes under solar light”, Environmental Nanotechnology, Monitoring & Management, 16: 100479, (2021). [8] Asahi, R., Morikawa, T., Ohwaki, T., Aoki, K., Taga, Y., “Visible-light photocatalysis in nitrogen-doped titanium oxides”, Science, 293: 269-271, (2001).
  • [9] Cheng, X., Yu, X., Xing, Z., “Characterization and mechanism analysis of N doped TiO2 with visible light response and its enhanced visible activity”, Applied Surface Science, 258(7): 3244-3248, (2012).
  • [10] Fu, J., Tian, Y., Chang, B., Xi, F., Dong, X., “Facile fabrication of N-doped TiO2 nanocatalyst with superior performance under visible light irradiation”, Journal of Solid State Chemistry, 199: 280-286, (2013). [11] Ansari, S.A., Khan, M.M., Ansari, M. O., Cho, M.H., “Nitrogen-doped titanium dioxide (N-doped TiO2) for visible light photocatalysis”, New Journal of Chemistry, 40: 3000-3009, (2016).
  • [12] Tian, G., Pan, K., Fu, H., Jing, L., Zhou, W., “Enhanced photocatalytic activity of S-doped TiO2-ZrO2 nanoparticles under visible-light irradiation”, Journal of Hazardous Materials, 166: 939-944, (2009).
  • [13] McManamon, C., O’Connell, J., Delaney, P., Rasappa, S., Holmes, J. D., Morris, M. A., “A facile route to synthesis of S-doped TiO2 nanoparticles for photocatalytic activity”, Journal of Molecular Catalysis A: Chemical, 406: 51-57, (2015).
  • [14] Lin, Y.-T., Weng, C.-H., Lin, Y.-H., Shiesh, C., Chen, F.-Y., “Effect of C content and calcination temperature on the photocatalytic activity of C-doped TiO2 catalyst”, Separation and Purification Technology, 116: 114-123, (2013). [15] Sullivan, J.J.A., Neville, E.M., Herron, R., Thampi, K. R., Mac Elroy, J.M.D., “Routes to visible light active C-doped TiO2 photocatalysts using carbon atoms from the Ti precursors”, Journal of Photochemistry and Photobiology A: Chemistry, 289: 60-65, (2014).
  • [16] Peng, F., Cai, L., Yu, H., Wang, H., Yang, J., “Synthesis and characterization of substitutional and interstitial nitrogen-doped titanium dioxides with visible light photocatalytic activity”, Journal of Solid State Chemistry, 181: 130-136, (2008).
  • [17] Asghar, A., Raman, A.A.A., Daud, W.M.A.W., “Advanced oxidation processes for in-situ production of hydrogen peroxide/hydroxyl radical for textile wastewater treatment: a review”, Journal of Cleaner Production, 87: 826-838, (2015). [18] Bilinska, L., Gmurek, M., Ledakowicz, S., “Comparison between industrial and simulated textile wastewater treatment by AOPs – Biodegradability, toxicity and cost assessment”, Chemical Engineering Journal, 306: 550-559, (2016).
  • [19] Ambigadevi, J., Kumar, S.P., Vo, D.V. N., Haran, S.H., Raghavan, T.N.S., “Recent developments in photocatalytic remediation of textile effluent using semiconductor based nanostructured catalyst: A review”, Journal of Environmental Chemical Engineering, 9:104881, (2021).
  • [20] Selvaraj, V., Karthikaa, T.S., Mansiya, C., Alagar, M., “An over review on recently developed techniques, mechanisms and intermediate involved in the advanced azo dye degradation for industrial applications”, Journal of Molecular Structure, 1224: 129195, (2021).
  • [21] Rochkind, M., Pasternak, S., Paz, Y., “Using dyes for evaluating photocatalytic properties: A critical review”, Molecules, 20: 88-110, (2015). [22] Akpan, U.G., Hameed, B.H., “Parameters affecting the photocatalytic degradation of dyes using TiO2-based photocatalysts: A review”, Journal of Hazardous Materials, 170: 520-529, (2009). [23] Collazzo, G.C., Foletto, E.L., Jahn, S.L., Villetti, M.A., “Degradation of Direct Black 38 dye under visible light and sunlight irradiation by N-doped anatase TiO2 as photocatalyst”, Journal of Environmental Management, 98: 107-111, (2012). [24] Yeber, M.C., Zamora, T., Álvarez, R., Medina, P., “N-doped titanium dioxide nanoparticles activated under visible light achieve the photocatalytic degradation of textile azo dye remazol brilliant blue R”, Desalination and Water Treatment, 151: 161–166, (2019). [25] Berktaş, A., Kartal, Ö.E., “Synthesis of N-Doped TiO2 by sol-gel method and investigation of its photocatalytic activity”, 11th National Congress on Chemical Engineering, Eskişehir, 174-177, (2014).
  • [26] Spurr, R.A., Myers, H., “Quantitative analysis of anatase-rutile mixtures with an X-Ray Diffractometer”, Analytical Chemistry, 29: 760-762, (1957).
  • [27] Lin, Y. H., Chiu, T. C., Hsueh, H. T., Chu, H., “N-doped TiO2 photo-catalyst for the degradation of 1, 2-dichloroethane under fluorescent light”, Applied Surface Science, 258: 1581-1586, (2011).
  • [28] Huang, W.C., Ting, J.M., “Novel nitrogen-doped anatase TiO2 mesoporous bead photocatalysts for enhanced visible light response”, Ceramics International, 43(13): 9992-9997, (2017).
  • [29] Kalantari, K., Kalbasi, M., Sonrabi, M., Royaee, S.J., “Synthesis and characterization of N-doped TiO2 nanoparticles and their application in photocatalytic oxidation of dibenzothiophene under visible light”, Ceramics International, 42(13): 14834-14842, (2016).
  • [30] Lee, S., Chou, I.S., Lee, D.K., Kim, D.W., Noh, T.H., Kwak, C.H., Park, S., Hong, K.S., Lee, J.-K., Jung, H.S., “Influence of nitrogen chemical states on photocatalytic activities of nitrogen-doped TiO2 nanoparticles under visible light”, Journal of Photochemistry and Photobiology A: Chemistry, 213: 129-135, (2010).
  • [31] Ma, Y., Zhang, J., Tian, B., Chen, F., Wang, L., “Synthesis and characterization of thermally stable Sm, N co-doped TiO2 with highly visible light activity”, Journal of Hazardous Materials, 182: 386-393, (2010).
  • [32] Gai, L., Mei, Q., Duan, X., Jiang, H., Zhou, G., Tian, Y., Lu, X., “Controlled synthesis of nitrogen-doped binary and ternary TiO2 nanostructures with enhanced visible-light catalytic activity”, Journal of Solid State Chemistry, 199: 271-279, (2013).
  • [33] Senthilnathan, J., Philip, L., “Photocatalytic degradation of lindane under UV and visible light using N-doped TiO2”, Chemical Engineering Journal, 161: 83-92, (2010).
  • [34] Din, M.İ., Khalid, R., Najeeb, J., Hussain, Z., “Fundamentals and photocatalysis of methylene blue dye using various nanocatalytic assemblies- a critical review”, Journal of Cleaner Production, 298: 126567, (2021).
  • [35] Damodar, R.A., You, S. J., “Performance of an integrated membrane photocatalytic reactor for the removal of Reactive Black 5”, Separation and Purification Technology, 71: 44-49, (2010).
  • [36] Turkish State Meteorological Service https://www.mgm.gov.tr/kurumici/radyasyon_iller.aspx?il=malatya Access date: 06.05.2021
There are 27 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Chemical Engineering
Authors

Aslı Berktaş 0000-0001-7032-0702

Özlem Esen Kartal 0000-0002-7510-5427

Project Number 2209/A
Publication Date June 1, 2022
Published in Issue Year 2022 Volume: 35 Issue: 2

Cite

APA Berktaş, A., & Kartal, Ö. E. (2022). Decolorization of Reactive Black 5 Using N-Doped TiO2. Gazi University Journal of Science, 35(2), 360-370. https://doi.org/10.35378/gujs.828761
AMA Berktaş A, Kartal ÖE. Decolorization of Reactive Black 5 Using N-Doped TiO2. Gazi University Journal of Science. June 2022;35(2):360-370. doi:10.35378/gujs.828761
Chicago Berktaş, Aslı, and Özlem Esen Kartal. “Decolorization of Reactive Black 5 Using N-Doped TiO2”. Gazi University Journal of Science 35, no. 2 (June 2022): 360-70. https://doi.org/10.35378/gujs.828761.
EndNote Berktaş A, Kartal ÖE (June 1, 2022) Decolorization of Reactive Black 5 Using N-Doped TiO2. Gazi University Journal of Science 35 2 360–370.
IEEE A. Berktaş and Ö. E. Kartal, “Decolorization of Reactive Black 5 Using N-Doped TiO2”, Gazi University Journal of Science, vol. 35, no. 2, pp. 360–370, 2022, doi: 10.35378/gujs.828761.
ISNAD Berktaş, Aslı - Kartal, Özlem Esen. “Decolorization of Reactive Black 5 Using N-Doped TiO2”. Gazi University Journal of Science 35/2 (June 2022), 360-370. https://doi.org/10.35378/gujs.828761.
JAMA Berktaş A, Kartal ÖE. Decolorization of Reactive Black 5 Using N-Doped TiO2. Gazi University Journal of Science. 2022;35:360–370.
MLA Berktaş, Aslı and Özlem Esen Kartal. “Decolorization of Reactive Black 5 Using N-Doped TiO2”. Gazi University Journal of Science, vol. 35, no. 2, 2022, pp. 360-7, doi:10.35378/gujs.828761.
Vancouver Berktaş A, Kartal ÖE. Decolorization of Reactive Black 5 Using N-Doped TiO2. Gazi University Journal of Science. 2022;35(2):360-7.

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