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Investigation of the Effect of Zeolite Usage on Pervaporation Performance in Polymeric Membranes

Yıl 2022, Cilt: 9 Sayı: 2, 819 - 828, 31.12.2022
https://doi.org/10.35193/bseufbd.1080547

Öz

In this study, sodium alginate/poly (vinyl alcohol)/clinoptilolite composite membrane was obtained for the separation of dimethylformamide/water mixture by pervaporation method. Cross-linked membranes were characterized by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA) and scanning electron microscope (SEM) instruments. Although the flux value (3.266 kg/m2 h) was found to be high, the desired result for selectivity could not be achieved. The activation energy for the 20% by weight DMF solution was measured as 3,720 kcal/mol. The effect of zeolite addition on membrane performance was investigated.

Kaynakça

  • Richardson, J. F., Harker, J. H., & Backhurst, J. R. (2002). Coulson and Richardson’s Chemical Engineering. Butterworth-Heinemann, Oxford, 2(5), 437-474.
  • Feng, X. & Huang, R.Y.M. (1997). Liquid separation by membrane pervaporation: A review. Industrial & Engineering Chemistry Research, 36, 1048-1066.
  • Athayde, A. L., Baker, R. W., Daniels, R., Le, M. H., & Ly, J. H. (1997). Pervaporation for wastewater treatment. Chemtech, 1, 34-39.
  • Aminabhavi, T. M., Naidu, B. V. K., Sridhar, S., & Rangarajan, R. (2005). Pervaporation separation of water-isopropanol mixtures using polymeric membranes: Modeling and simulation aspects. Journal of Applied Polymer Science, 295, 1143-1153.
  • Alghezawi, N., Şanlı, O., Aras, L., & Asman, G. (2005). Separation of acetic acid-water mixtures through acrylonitrile grafted poly(vinyl alcohol) membranes by pervaporation. Chemical Engineering Processessing, 44, 51-58.
  • Rhim, J. M., Sohn, M. Y., Joo, H. J., & Lee, K. H. (1993). Pervaporation separation of binary organic aqueous liquid mixtures using crosslinked PVA membranes. I. Characterization of the reaction between PVA and PAA. Journal of Applied Polymer Science, 50, 679-684.
  • Nam, S. Y., Chun, H. J., & Lee, Y. M. (1999). Pervaporation separation of water-isopropanol mixture using carboxymethylated poly(vinyl alcohol) composite membranes. Journal of Applied Polymer Science, 72, 241-249.
  • Kittur, A. A., Tambe, S. M., Kulkarni, S. S., & Kariduraganavar, M. Y. (2004). Pervaporation separation of water-acetic acid mixtures through NaY zeolite incorporated sodium alginate membranes. Journal of Applied Polymer Science, 94, 2101-2109.
  • Kurkuri, M. D., Toti, U. S., & Aminabhavi, T. M. (2002). Syntehesis and characterization of blend membranes of sodium alginate and poly(vinyl alcohol) for the pervaporation separation of water + isopropanol mixtures. Journal of Applied Polymer Science, 86, 3642-3651.
  • Toti, U. S. & Aminabhavi, T. M. (2004). Different viscosity grade sodium alginate and modified sodium alginate membranes in pervaporation separationof water + acetic acid and water + isopropanol mixtures. Journal of Membrane Science, 228(2), 199-208.
  • Wang, S. & Peng, Y. (2010). Natural zeolites as effective adsorbents in water and wastewater treatment, Department of Chemical Engineering, Curtin University of Technology, Australia, College of Environmental and Energy Engineering, Beijing University of Technology, Chemical Engineering Journal, 11-24.
  • Nagrockiene, D. & Girskas, G. (2016). Research into the properties of concrete modified with natural zeolite, Addition, a Department of Building Materials, Vilnius Gediminas Technical University, Lithuania, Research Institute of Buildings Materials and Products, Vilnius Gediminas Technical University. Construction and Building Materials 113, 964-969.
  • Bhat, S. D. & Aminabhavi, T. M. (2006). Novel sodium alginate composite membranes incorporated with SBA-15 molecular sieves for the pervaporation dehydration of aqueous mixtures of isopropanol and 1,4-dioxane at 30 oC. Microporous Mesoporous Materials, 91, 206-214.
  • Naidu, B. V. K., Bhat, S. D., Sairam, M., Wali, A. C., Sawant, D. P., Halligudi, S. B., Mallikarjuna, N. N., & Aminabhavi, T. M. (2005). Comparison of the pervaporation separation of a water-acetonitrile mixture with zeolite-filled-polyaniline semi interpenetrating polymer network membranes. Journal of Applied Polymer Science, 96, 1968- 1978.
  • Mallikarjunagouda, B. P. & Aminabhavi, T. M. (2008).Pervaporation separation of toluene/alcohol mixtures using silicalite zeolite embedded chitosan mixed matrix membranes. Separation and Purifcation Technology, 62, 128-136.
  • Kahya, S., Kondolot Solak, E., & Şanlı, O. (2010). Sodium alginate/poly(vinyl alcohol) alloy membranes for the pervaporation, vapor permeation and vapor permeation with temperature difference separation of dimethylformamide/water mixtures: A comparative study. Vacuum, 84, 1092-1101.
  • Huang, Z., Ru, X., Zhu, Y. T., Guo, Y., & Teng, L. (2019). Poli(vinyl alcohol)/ZSM-5 zeolite mixed matrix membranes for pervaporation dehydration of isopropanol/water solution through response surface methodology. Chemical Engineering Research and Design, 144, 19-34.
  • Tsai, H. A., Hsu, C. Y., Huang, S. H., Lee, K. R., & Hung, W. S. (2018). The preparation of polyelectrolyte/hydrolyzed polyacrylonitrile composite hollow fiber membrane for pervaporation. Journal of Taiwan Institue of Chemical Engineers, 91, 623-633.
  • Kahya, S., Şanlı, O., & Çamurlu, E. (2011). Crosslinked sodium alginate and sodium alginate-clinoptilolite (natural zeolite) composite membranes for pervaporation separation of dimethylformamide-water mixtures: A comparative study. Desalination and Water Treatment, 25, 297-309.
  • Kahya, S. & Şanlı, O. (2014). Separation of dimethylformamide/water mixtures through sodium alginate and sodium alginate/clinoptilolite composite membranes by vapor permeation with and without feed-membrane temperature difference. Desalination and Water Treatment, 52, 3517-3525.

Polimerik Membranlarda Zeolit Kullanımının Pervaporasyon Performansı Üzerine Etkisinin İncelenmesi

Yıl 2022, Cilt: 9 Sayı: 2, 819 - 828, 31.12.2022
https://doi.org/10.35193/bseufbd.1080547

Öz

Bu çalışmada, pervaporasyon yöntemiyle dimetilformamit/su karışımının ayrılması amacıyla sodyum aljinat/poli (vinil alkol)/klinoptilolit kompozit membran elde edilmiştir. Çapraz bağlı membranlar, (FTIR), diferansiyel taramalı kalorimetre (DSC), termal gravimetrik analiz (TGA) ve taramalı elektron mikroskobu (SEM) cihazları ile karakterize edilmiştir. Akı değeri (3,266 kg/m2 sa) yüksek bulunmasına karşın, seçicilik için arzulanan sonuca ulaşılamamıştır. Ağırlıkça % 20 DMF çözeltisi için aktivasyon enerjisi 3,720 kcal/mol olarak ölçülmüştür. Zeolit ilavesinin membran performansına etkisi araştırılmıştır.

Kaynakça

  • Richardson, J. F., Harker, J. H., & Backhurst, J. R. (2002). Coulson and Richardson’s Chemical Engineering. Butterworth-Heinemann, Oxford, 2(5), 437-474.
  • Feng, X. & Huang, R.Y.M. (1997). Liquid separation by membrane pervaporation: A review. Industrial & Engineering Chemistry Research, 36, 1048-1066.
  • Athayde, A. L., Baker, R. W., Daniels, R., Le, M. H., & Ly, J. H. (1997). Pervaporation for wastewater treatment. Chemtech, 1, 34-39.
  • Aminabhavi, T. M., Naidu, B. V. K., Sridhar, S., & Rangarajan, R. (2005). Pervaporation separation of water-isopropanol mixtures using polymeric membranes: Modeling and simulation aspects. Journal of Applied Polymer Science, 295, 1143-1153.
  • Alghezawi, N., Şanlı, O., Aras, L., & Asman, G. (2005). Separation of acetic acid-water mixtures through acrylonitrile grafted poly(vinyl alcohol) membranes by pervaporation. Chemical Engineering Processessing, 44, 51-58.
  • Rhim, J. M., Sohn, M. Y., Joo, H. J., & Lee, K. H. (1993). Pervaporation separation of binary organic aqueous liquid mixtures using crosslinked PVA membranes. I. Characterization of the reaction between PVA and PAA. Journal of Applied Polymer Science, 50, 679-684.
  • Nam, S. Y., Chun, H. J., & Lee, Y. M. (1999). Pervaporation separation of water-isopropanol mixture using carboxymethylated poly(vinyl alcohol) composite membranes. Journal of Applied Polymer Science, 72, 241-249.
  • Kittur, A. A., Tambe, S. M., Kulkarni, S. S., & Kariduraganavar, M. Y. (2004). Pervaporation separation of water-acetic acid mixtures through NaY zeolite incorporated sodium alginate membranes. Journal of Applied Polymer Science, 94, 2101-2109.
  • Kurkuri, M. D., Toti, U. S., & Aminabhavi, T. M. (2002). Syntehesis and characterization of blend membranes of sodium alginate and poly(vinyl alcohol) for the pervaporation separation of water + isopropanol mixtures. Journal of Applied Polymer Science, 86, 3642-3651.
  • Toti, U. S. & Aminabhavi, T. M. (2004). Different viscosity grade sodium alginate and modified sodium alginate membranes in pervaporation separationof water + acetic acid and water + isopropanol mixtures. Journal of Membrane Science, 228(2), 199-208.
  • Wang, S. & Peng, Y. (2010). Natural zeolites as effective adsorbents in water and wastewater treatment, Department of Chemical Engineering, Curtin University of Technology, Australia, College of Environmental and Energy Engineering, Beijing University of Technology, Chemical Engineering Journal, 11-24.
  • Nagrockiene, D. & Girskas, G. (2016). Research into the properties of concrete modified with natural zeolite, Addition, a Department of Building Materials, Vilnius Gediminas Technical University, Lithuania, Research Institute of Buildings Materials and Products, Vilnius Gediminas Technical University. Construction and Building Materials 113, 964-969.
  • Bhat, S. D. & Aminabhavi, T. M. (2006). Novel sodium alginate composite membranes incorporated with SBA-15 molecular sieves for the pervaporation dehydration of aqueous mixtures of isopropanol and 1,4-dioxane at 30 oC. Microporous Mesoporous Materials, 91, 206-214.
  • Naidu, B. V. K., Bhat, S. D., Sairam, M., Wali, A. C., Sawant, D. P., Halligudi, S. B., Mallikarjuna, N. N., & Aminabhavi, T. M. (2005). Comparison of the pervaporation separation of a water-acetonitrile mixture with zeolite-filled-polyaniline semi interpenetrating polymer network membranes. Journal of Applied Polymer Science, 96, 1968- 1978.
  • Mallikarjunagouda, B. P. & Aminabhavi, T. M. (2008).Pervaporation separation of toluene/alcohol mixtures using silicalite zeolite embedded chitosan mixed matrix membranes. Separation and Purifcation Technology, 62, 128-136.
  • Kahya, S., Kondolot Solak, E., & Şanlı, O. (2010). Sodium alginate/poly(vinyl alcohol) alloy membranes for the pervaporation, vapor permeation and vapor permeation with temperature difference separation of dimethylformamide/water mixtures: A comparative study. Vacuum, 84, 1092-1101.
  • Huang, Z., Ru, X., Zhu, Y. T., Guo, Y., & Teng, L. (2019). Poli(vinyl alcohol)/ZSM-5 zeolite mixed matrix membranes for pervaporation dehydration of isopropanol/water solution through response surface methodology. Chemical Engineering Research and Design, 144, 19-34.
  • Tsai, H. A., Hsu, C. Y., Huang, S. H., Lee, K. R., & Hung, W. S. (2018). The preparation of polyelectrolyte/hydrolyzed polyacrylonitrile composite hollow fiber membrane for pervaporation. Journal of Taiwan Institue of Chemical Engineers, 91, 623-633.
  • Kahya, S., Şanlı, O., & Çamurlu, E. (2011). Crosslinked sodium alginate and sodium alginate-clinoptilolite (natural zeolite) composite membranes for pervaporation separation of dimethylformamide-water mixtures: A comparative study. Desalination and Water Treatment, 25, 297-309.
  • Kahya, S. & Şanlı, O. (2014). Separation of dimethylformamide/water mixtures through sodium alginate and sodium alginate/clinoptilolite composite membranes by vapor permeation with and without feed-membrane temperature difference. Desalination and Water Treatment, 52, 3517-3525.
Toplam 20 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Bölüm Makaleler
Yazarlar

Suat Kahya 0000-0002-1660-5771

Yayımlanma Tarihi 31 Aralık 2022
Gönderilme Tarihi 28 Şubat 2022
Kabul Tarihi 27 Haziran 2022
Yayımlandığı Sayı Yıl 2022 Cilt: 9 Sayı: 2

Kaynak Göster

APA Kahya, S. (2022). Polimerik Membranlarda Zeolit Kullanımının Pervaporasyon Performansı Üzerine Etkisinin İncelenmesi. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi, 9(2), 819-828. https://doi.org/10.35193/bseufbd.1080547