Airbrushed PSF/ZnO Composite Coatings as a Novel Approach for the Consolidation of Historical Bones
Abstract
:1. Introduction
2. Experimental Part
2.1. Materials
2.2. Sample Preparation
2.3. Characterization
2.3.1. Structural and Morphological Characterization
2.3.2. Mechanical Characterization
3. Results and Discussion
3.1. Morphological Characterization
3.2. Structural Characterization
3.3. Thermal Characterization
3.4. Mechanical Characterization
3.5. Mechanical Characterization of the PSF/ZnO Surface Treatment: Martens Hardness Measurements
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Description of the Treatment 1 | Sample Code |
---|---|
Untreated Bone | UNB |
Treated sample with 5% PSF | 5P |
Treated sample with 5% PSF + 1% ZnO | 5P-1Z |
Treated sample with 5% PSF + 2% ZnO | 5P-2Z |
Treated sample with 5% PSF + 5% ZnO | 5P-5Z |
Treated sample with 5% PSF + 10% ZnO | 5P-10Z |
Samples | Initial Mass | Final Mass | DTGA | |||
---|---|---|---|---|---|---|
Sample Name | Mass (mg) | Mass (mg) | Mass (%) | Change in Final Mass (%) 1 | Slope after Pyrolysis (%·°C−1) | Tpeak (°C) |
PSF | 4.5354 | 1.3742 | 30.3 | 0 | −1.78 | 535 |
PSF + 1%ZnO | 6.1185 | 2.0375 | 33.3 | 3.0 | −1.83 | 536 |
PSF + 2% ZnO | 6.1494 | 2.0478 | 33.3 | 3.0 | −1.72 | 536 |
PSF + 5% ZnO | 9.1104 | 3.5066 | 38.49 | 8.2 | −1.64 | 538 |
PSF + 10% ZnO | 4.7485 | 1.9649 | 41.38 | 11.1 | −1.55 | 539 |
Sample Name | σ (MPa) | Eexp (MPa) | Eupper (MPa) | Elow (MPa) | K | Strain to Failure (%) | Stress to Failure (MPa) | Total Area (106 J·m−3) |
---|---|---|---|---|---|---|---|---|
PSF | 9.52 ± 2.80 | 541 ± 229.7 | 546 | 541 | 0 | 2.31± 1.08 | 9.14 ± 4.13 | 0.1 ± 0.07 |
PSF + 1% ZnO | 22.26 ± 4.36 | 822 ± 175.5 | 784 | 542.15 | 1.00 | 3.90 ± 1.43 | 21.91 ± 4.59 | 0.57 ± 0.35 |
PSF + 2% ZnO | 25.45 ± 4.40 | 803 ± 237.8 | 1038 | 543.43 | 0.528 | 4.91 ± 1.52 | 23.03 ± 4.83 | 0.84 ± 0.33 |
PSF + 5% ZnO | 26.13 ± 5.47 | 836 ± 220.9 | 1811 | 547.26 | 0.236 | 8.12 ± 2.69 | 25.87 ± 5.80 | 1.22 ± 0.57 |
PSF + 10% ZnO | 27.98 ± 6.24 | 1016 ± 361 | 3192 | 554.24 | 0.124 | 6.43 ± 2.19 | 27.35 ± 5.59 | 1.28 ± 0.60 |
Sample | HM (N·mm−2) | hmax (μm) | HUplast (N mm−2) | Welast (Nmm) | Welast (Nmm) |
---|---|---|---|---|---|
UNB | 139.4 ± 50.2 | 52.0 ± 0.5 | 202.8 ± 29.4 | 0.05030 ± 0.0010 | 0.1860 ± 0.0460 |
5P | 282.3 ± 47.4 | 36.7 ± 3.2 | 437.4 ± 89.8 | 0.047590 ± 0.0007 | 0.97524 ± 0.032 |
5P-1Z | 850.1 ± 50.3 | 21.0 ± 0.5 | 1916.4 ± 172.2 | 0.04246 ± 0.0010 | 0.04613 ± 0.0042 |
5P-2Z | 625.3 ± 75.7 | 25.0 ± 1.5 | 1248.6 ± 166.2 | 0.04512 ± 0.0063 | 0.06055 ± 0.0130 |
5P-5Z | 543.5 ± 107.9 | 26.4 ± 2.3 | 940.3 ± 259.9 | 0.03593 ± 0.0012 | 0.08168 ± 0.0170 |
5P-10Z | 173.3 ± 26.3 | 46.9 ± 3.7 | 321.3 ± 70.9 | 0.06990 ± 0.0026 | 0.01575 ± 0.0084 |
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Moradienayat, M.; González-Benito, J.; Olmos, D. Airbrushed PSF/ZnO Composite Coatings as a Novel Approach for the Consolidation of Historical Bones. Nanomaterials 2023, 13, 625. https://doi.org/10.3390/nano13040625
Moradienayat M, González-Benito J, Olmos D. Airbrushed PSF/ZnO Composite Coatings as a Novel Approach for the Consolidation of Historical Bones. Nanomaterials. 2023; 13(4):625. https://doi.org/10.3390/nano13040625
Chicago/Turabian StyleMoradienayat, Monireh, Javier González-Benito, and Dania Olmos. 2023. "Airbrushed PSF/ZnO Composite Coatings as a Novel Approach for the Consolidation of Historical Bones" Nanomaterials 13, no. 4: 625. https://doi.org/10.3390/nano13040625