Assessment of the Impact of a Motorway on Content andSpatial Distribution of Mercury in Adjacent Agricultural Soils
Abstract
:1. Introduction
2. Materials and Method
2.1. Study Area and Sampling Procedur
2.2. Laboratory Analysis:
2.2.1. Selected Physical and Chemical Properties
2.2.2. Mercury Content
2.3. Statistical and Geostatistical Analyses
2.4. Pollution Indices
3. Results
4. Conclusions
- The total mercury content ranged from 0.013 to 0.041 mg·kg−1 in the surface layers and from 0.013 to 0.059 mg·kg−1 in the subsurface layers, which qualifies the study area as uncontaminated by mercury.
- The correlation coefficients confirmed a significant positive relationship between total carbon content and total mercury content.
- The geo-accumulation coefficient shows no harmful values.
- The enrichment factor indicates a natural or moderate source of this element in the field, except at one point, where the contamination factor was very high.
- Analysis of Moran’s I spatial correlation showed a lack of spatial dependence between tested points, which may evidence that the motorway does not affect mercury contents in the soil.
- The elevated mercury content at a single test point may indicate a random event unrelated to the motorway’s operation.
- The geochemical monitoring of soil is important in the aim of evaluating the natural content of mercury in soils, related to parental materials and possible enrichment due to human activities.
Author Contributions
Funding
Conflicts of Interest
References
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No | Depth [cm] | pH H2O | pH KCl | TOC [g.kg−1] | CaCO3 [%] |
---|---|---|---|---|---|
1 | 0–20 20–40 | 7.6 7.6 | 7.2 7.2 | 3.8 2.6 | <1 <1 |
2 | 0–20 20–40 | 7.0 7.3 | 6.5 6.8 | 8.6 5.4 | <1 <1 |
3 | 0–20 20–40 | 7.1 7.0 | 6.5 6.3 | 4.2 2.7 | <1 <1 |
4 | 0–20 20–40 | 7.1 7.2 | 6.5 6.8 | 2.7 9.3 | <1 <1 |
5 | 0–20 20–40 | 7.4 7.5 | 7.1 7.2 | 9.3 5.6 | 1.3 1.4 |
6 | 0–20 20–40 | 7.4 7.1 | 7.1 6.4 | 3.9 2.0 | <1 <1 |
7 | 0–20 20–40 | 7.4 7.1 | 7.0 6.3 | 2.9 1.9 | <1 <1 |
8 | 0-20 20–40 | 7.3 7.2 | 6.9 6.8 | 2.1 3.2 | <1 <1 |
9 | 0–20 20–40 | 7.6 7.7 | 7.2 7.3 | 1.8 1.5 | 4.6 5.3 |
10 | 0–20 20–40 | 7.6 8.0 | 7.3 7.4 | 4.6 0.9 | 1.4 5.6 |
11 | 0–20 20–40 | 7.2 7.1 | 6.9 6.6 | 5.5 4.0 | <1 <1 |
12 | 0–20 20–40 | 7.3 7.3 | 7.1 7.0 | 7.7 6.5 | <1 <1 |
13 | 0–20 20–40 | 7.5 7.5 | 7.1 7.2 | 6.3 7.6 | 1.3 1.5 |
14 | 0–20 20–40 | 7.3 7.2 | 6.8 6.8 | 4.6 4.9 | <1 <1 |
15 | 0–20 20–40 | 7.8 7.7 | 7.3 7.3 | 1.9 1.5 | 2.3 2.8 |
16 | 0–20 20–40 | 7.1 7.2 | 6.8 6.8 | 4.3 5.7 | <1 <1 |
17 | 0–20 20–40 | 6.0 6.4 | 5.3 5.6 | 6.9 5.6 | <1 <1 |
18 | 0–20 20–40 | 7.4 7.7 | 7.2 7.3 | 4.9 6.2 | 1.3 3.9 |
19 | 0–20 20–40 | 6.9 7.4 | 6.8 6.6 | 10.7 3.9 | <1 <1 |
20 | 0–20 20–40 | 7.6 7.9 | 7.2 7.3 | 3.6 2.9 | 2.0 6.4 |
No. | Depth (cm) | Hg (mg·kg−1) | Fe | Igeo Index | EF |
---|---|---|---|---|---|
1 | 0–20 | 0.039 | 962.30 | −0.23 | 3.90 |
20–40 | 0.027 | 957.80 | −0.61 | 2.65 | |
2 | 0–20 | 0.025 | 907.20 | −0.65 | 2.41 |
20–40 | 0.025 | 908.40 | −0.68 | 2.33 | |
3 | 0–20 | 0.021 | 894.70 | −0.82 | 2.00 |
20–40 | 0.022 | 877.20 | −0.80 | 2.01 | |
4 | 0–20 | 0.027 | 861.30 | −0.59 | 2.41 |
20–40 | 0.033 | 866.50 | −0.39 | 2.97 | |
5 | 0–20 | 0.039 | 975.20 | −0.23 | 3.93 |
20–40 | 0.016 | 1000.60 | −1.14 | 1.63 | |
6 | 0–20 | 0.025 | 1114.10 | −0.66 | 2.93 |
20–40 | 0.028 | 1116.00 | −0.56 | 3.24 | |
7 | 0–20 | 0.024 | 1115.50 | −0.70 | 2.81 |
20–40 | 0.025 | 1070.50 | −0.66 | 2.82 | |
8 | 0–20 | 0.024 | 981.90 | −0.70 | 2.47 |
20–40 | 0.025 | 959.40 | −0.65 | 2.54 | |
9 | 0–20 | 0.021 | 1082.00 | −0.86 | 2.32 |
20–40 | 0.021 | 1040.20 | −0.85 | 2.25 | |
10 | 0–20 | 0.024 | 946.90 | −0.70 | 2.39 |
20–40 | 0.022 | 1053.60 | −0.78 | 2.46 | |
11 | 0–20 | 0.032 | 935.10 | −0.41 | 3.16 |
20–40 | 0.036 | 923.90 | −0.30 | 3.48 | |
12 | 0–20 | 0.028 | 981.50 | −0.56 | 2.85 |
20–40 | 0.029 | 992.90 | −0.52 | 3.01 | |
13 | 0–20 | 0.025 | 1086.60 | −0.66 | 2.86 |
20–40 | 0.034 | 981.90 | −0.37 | 3.45 | |
14 | 0–20 | 0.022 | 971.70 | −0.80 | 2.21 |
20–40 | 0.018 | 960.60 | −0.97 | 1.84 | |
15 | 0–20 | 0.025 | 991.60 | −0.67 | 2.59 |
20–40 | 0.013 | 972.00 | −1.30 | 1.34 | |
16 | 0–20 | 0.029 | 886.70 | −0.51 | 2.69 |
20–40 | 0.037 | 921.90 | −0.26 | 3.60 | |
17 | 0–20 | 0.032 | 831.40 | −0.42 | 2.78 |
20–40 | 0.033 | 829.80 | −0.39 | 2.85 | |
18 | 0–20 | 0.041 | 1001.20 | −0.18 | 4.25 |
20–40 | 0.059 | 1024.30 | 0.19 | 6.31 | |
19 | 0–20 | 0.025 | 1067.20 | −0.66 | 2.80 |
20–40 | 0.030 | 1107.30 | −0.49 | 3.43 | |
20 | 0–20 | 0.013 | 942.70 | −1.29 | 1.31 |
20–40 | 0.018 | 952.50 | −0.97 | 1.83 |
Element Hg mg/kg | Statistical Parameters | ||||||
---|---|---|---|---|---|---|---|
Average | Min | Max. | SD | Skewness | Kurtosis | CV (%) | |
0–20 cm | 0.028 | 0.013 | 0.046 | 0.007 | 0.82 | 1.37 | 26.61 |
20–40 cm | 0.028 | 0.013 | 0.059 | 0.01 | 1.58 | 4.45 | 36.03 |
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Jaworska, H.; Klimek, J. Assessment of the Impact of a Motorway on Content andSpatial Distribution of Mercury in Adjacent Agricultural Soils. Minerals 2021, 11, 1221. https://doi.org/10.3390/min11111221
Jaworska H, Klimek J. Assessment of the Impact of a Motorway on Content andSpatial Distribution of Mercury in Adjacent Agricultural Soils. Minerals. 2021; 11(11):1221. https://doi.org/10.3390/min11111221
Chicago/Turabian StyleJaworska, Hanna, and Joanna Klimek. 2021. "Assessment of the Impact of a Motorway on Content andSpatial Distribution of Mercury in Adjacent Agricultural Soils" Minerals 11, no. 11: 1221. https://doi.org/10.3390/min11111221