1992 年 16 巻 2 号 p. 159-162
The effects of nitrogenation on the magnetic properties of Sm2(Fe0.9M0.1)17C1.6 (M=Ga, Cr) melt-spun ribbons were studied. The melt-spun amorphous ribbons were crystallized at above 550°C in forming TbCu7 phase, and they were further transformed to Th2Zn17 phase above 680°C on heating. The nitrogenation at 550°C for 4 h enhances the magnetic properties of annealed ribbons. The Sm2(Fe0.9Cr0.1)17C1.6 ribbon annealed at 650°C which consists of TbCu7 phase, exhibits high (BH)max, of 11.0 MGOe after nitrogenation. The Sm2(Fe0.9Cr0.1)17C1.6 ribbon annealed at 725°C. which consists of Th2Zn17 phase, shows high coercivity of 19.0 kOe with (BH)max, of 7.4 MGOe after nitrogenation.