ESTIMATION OF EFFICIENCY OF OXALIC ACID APPLICATION IN SOLUTION COMBUSTION SYNTHESIS OF CATALYST FOR PRODUCTION OF HYDROGEN AND CARBON FROM METHANE

P. B. Kurmashov; Курмашов П. Б.; M. V. Popov; Попов М. В.; A. E. Brester; Брестер А. Е.; A. V. Ukhina; Ухина А. В.; A. G. Bannov; Баннов А. Г.

doi:10.31857/S2686953522600660

ESTIMATION OF EFFICIENCY OF OXALIC ACID APPLICATION IN SOLUTION COMBUSTION SYNTHESIS OF CATALYST FOR PRODUCTION OF HYDROGEN AND CARBON FROM METHANE

Authors: Kurmashov P.B.¹, Popov M.V.¹^,2, Brester A.E.¹, Ukhina A.V.³, Bannov A.G.¹
Affiliations:
1. Novosibirsk State Technical University
2. N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences
3. Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences
Issue: Vol 511, No 1 (2023)
Pages: 68-76
Section: ХИМИЧЕСКАЯ ТЕХНОЛОГИЯ
URL: https://journals.rcsi.science/2686-9535/article/view/135987
DOI: https://doi.org/10.31857/S2686953522600660
EDN: https://elibrary.ru/YRQGXE
ID: 135987

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Abstract
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Abstract

In this work, the parameters of catalyst synthesis by solution combustion method using oxalic acid as a reducing agent, were investigated. The catalysts activity in the process of obtaining hydrogen and carbon nanofibers by the catalytic decomposition of methane has been determined. The effectiveness of using this reagent for the preparation of a nickel catalyst (90% Ni/10% Al₂O₃) that does not require preliminary reduction with hydrogen was shown. Based on the regression analysis, it was found that among the catalyst synthesis parameters, the yields of carbon and hydrogen are most strongly influenced by temperature.

Keywords

methane decomposition, hydrogen, carbon nanofibers, solution combustion, oxalic acid

References

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