Structural Changes during Polymerization of Acrylamide in Semidilute Solutions of Wormlike Surfactant Micelles

A. S. Ospennikov; Оспенников А. С.; A. V. Shibaev; Шибаев А. В.; A. I. Kuklin; Куклин А. И.; O. E. Philippova; Филиппова О. Е.

doi:10.31857/S2308112023600060

Structural Changes during Polymerization of Acrylamide in Semidilute Solutions of Wormlike Surfactant Micelles

Authors: Ospennikov A.S.¹, Shibaev A.V.¹, Kuklin A.I.²^,3, Philippova O.E.¹
Affiliations:
1. Faculty of Physics, Moscow State University
2. Joint Institute for Nuclear Research
3. Moscow Institute of Physics and Technology
Issue: Vol 65, No 5 (2023)
Pages: 327-332
Section: РАСТВОРЫ
URL: https://journals.rcsi.science/2308-1120/article/view/233616
DOI: https://doi.org/10.31857/S2308112023600060
EDN: https://elibrary.ru/DBWHGH
ID: 233616

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Abstract

The structure and rheological properties of aqueous solutions of the anionic surfactant potassium oleate and the water-soluble monomer acrylamide before and after radical polymerization have been studied. In the absence of monomer and in the presence of a low-molecular-weight salt, potassium oleate forms a network of long entangled cylindrical (wormlike) micelles. The addition of the monomer does not lead to a change in their cylindrical shape and radius, but it promotes the transformation of branched micelles into linear ones. The structure of surfactant aggregates changes significantly after polymerization: according to neutron scattering data, it becomes bicontinuous and its local geometry becomes lamellar. The coexistence of such a structure with polyacrylamide macromolecules in a semidilute solution leads to a significant synergistic increase in viscosity and elastic modulus.

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