Email this article On the Possibility of Thermokinetic Oscillations in the Reaction of Methane Oxidation on Nickel
- Authors: Peskov N.V.1, Slinko M.M.2
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Affiliations:
- Moscow State University named after M.V. Lomonosov, Faculty of Computational Mathematics and Cybernetics
- Semenov Institute of Chemical Physics of the Russian Academy of Sciences
- Issue: Vol 64, No 3 (2023)
- Pages: 317-325
- Section: Articles
- URL: https://journals.rcsi.science/0453-8811/article/view/137008
- DOI: https://doi.org/10.31857/S0453881123030085
- ID: 137008
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Abstract
The paper demonstrates the possibility of occurrence of thermokinetic oscillations during the methane oxidation on a nickel industrial catalyst at real values of the parameters. It is shown that reaction rate oscillations can originate under the conditions of short contact times and in the region where periodic oxidation–reduction processes do not occur. The origin of these thermokinetic oscillations is the periodic blocking of the surface with carbon and its cleaning by removing carbon from the catalyst surface.
About the authors
N. V. Peskov
Moscow State University named after M.V. Lomonosov, Faculty of Computational Mathematics and Cybernetics
Email: slinko@polymer.chph.ras.ru
Russia, 119992, Moscow, Leninskie Gory
M. M. Slinko
Semenov Institute of Chemical Physics of the Russian Academy of Sciences
Author for correspondence.
Email: slinko@polymer.chph.ras.ru
Russia, 119991, Moscow, Kosygin str., 4
References
- Slinko M.M., Jaeger N. Appendix-Oscillatory Heterogeneous Catalytic Systems // Catal. Today. 2005. V. 105. P. I–II.
- Слинько М.М., Макеев А.Г. // Кинетика и катализ. 2020. Т. 61. № 4. С. 1.
- Bychkov V.Yu., Tyulenin Yu.P., Korchak V.N., Aptekar E.L. // Appl. Catal. A: Gen. 2006. V. 304. P. 21.
- Zhang X., Hayward D.O., Mingos D.M.P. // Catal. Lett. 2003. V. 86. P. 235.
- Zhang X., Hayward D.O., Mingos D.M.P. // Catal. Lett. 2002. V. 83 P. 149.
- Сараев А.А., Косолобов С.С., Каичев В.В., Бухтияров В.И. // Кинетика и катализ. 2015. Т. 56. № 5. С. 606
- Saraev A.A., Vinokurov Z.S., Kaichev V.V., Shmakov A.N., Bukhtiyarov V.I. // Catal. Sci. Technol. 2017. V. 7. P. 1646.
- Hu Y.H., Ruckenstein E. // J. Phys. Chem. A. 1998. V. 102. P. 10568.
- Jin R., Chen Y., Li W., Cui W., Ji Y., Yu C., Jiang Y. // Appl. Catal. A: Gen. 2000. V. 201. P. 71.
- Slinko M.M., Korchak V.N., Peskov N.V. // Appl. Catal. A: Gen. 2006. V. 303. P. 258.
- Bychkov V.Y., Tyulenin Y.P., Slinko M.M., Gorenberg A.Ya., Korchak V.N. // Catal. Lett. 2017. V. 147. P. 2664.
- Lashina E.A., Kaichev V.V., Saraev A.A., Ustugov V.V., Chumakova N.A., Chumakov G.A., Bukhtiyarov V.I. // J. Phys. Chem. A. 2017. V. 121. P. 6874.
- Delgado K.H., Maier L., Tischer S., Zellner A., Stotz H., Deutschmann O. // Catalysts. 2015. V. 5. P. 871.
- Шусторович Е.М., Зейгарник А.В. // Ж. Физ. Химии. 2006. Т. 80. С. 8.
- Sault A.G., Goodman D.W. // J. Chem. Phys. 1988. V. 88. P. 7232.
- Stuckless J.T., Wartnaby C.E., Al-Sarraf N., Dixon-Warren St.J.B., Kovar M., King D.A. // J. Chem. Phys. 1997. V. 106. P. 2012.
- Франк-Каменецкий Д.А. Диффузия и теплопередача в химической кинетике. Москва: Наука, 1967.
- Gray P., Scott S.K. Chemical Oscillations and Instabilities: Nonlinear Chemical Kinetics. Oxford: Oxford University Press, 1990.
- Chang M., Schmitz R.A. // Chem. Eng. Sci. 1975. V. 30. P.21.
- Слинько М.Г. // Кинетика и Катализ, 1960. Т. 1. С. 153.
- Ray W.H., Hastings S.P. // Chem. Eng. Sci. 1980. V. 35. P. 589.
- Slinko M.M., Jaeger N.I. // Stud. Surf. Sci. Catal. 1994. V. 86. P. 1.
- Wicke E., Kummann P., Keil W., Schiefler J. // Ber. Bunsenges. Phys. Chem. 1980. V. 84. P. 315.
- Schüth F., Song X., Schmidt L.D., Wicke E. // J. Phys. Chem. 1990. V. 92. P. 745.
- Hickman D.A., Schmidt L.D. // J. Catal. 1992. V. 138. P. 267.
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