FEATURES OF THE ELECTROCHEMICAL BEHAVIOR OF CHLOROPHENOXY SUBSTITUTED COBALT AND COPPER PHTHALOCYANINATES IN NON-AQUEOUS MEDIA

M. A. Kovanova; Кованова М. А.; T. V. Tikhomirova; Тихомирова Т. В.; I. F. Sakhapov; Сахапов И. Ф.; Z. N. Gafurov; Гафуров З. Н.; D. G. Yakhvarov; Яхваров Д. Г.; A. S. Vashurin; Вашурин А. С.

doi:10.31857/S0424857023090074

FEATURES OF THE ELECTROCHEMICAL BEHAVIOR OF CHLOROPHENOXY SUBSTITUTED COBALT AND COPPER PHTHALOCYANINATES IN NON-AQUEOUS MEDIA

Authors: Kovanova M.A.¹, Tikhomirova T.V.¹, Sakhapov I.F.², Gafurov Z.N.², Yakhvarov D.G.², Vashurin A.S.¹
Affiliations:
1. Ivanovo State University of Chemistry and Technology
2. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences
Issue: Vol 59, No 9 (2023)
Pages: 495-500
Section: Articles
URL: https://journals.rcsi.science/0424-8570/article/view/139369
DOI: https://doi.org/10.31857/S0424857023090074
EDN: https://elibrary.ru/MIQFLM
ID: 139369

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Abstract
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Abstract

The electrochemical behavior of tetra-4-[4-(2,4,5-trichlorophenoxy)]phthalocyaninates of cobalt(II) (CoPc) and copper(II) (CuPc) in N,N-dimethylformamide 0.1 M nBu4NBF4 was studied by cyclic voltammetry. It has been experimentally established that both metal complexes are capable of irreversible reduction. In the reverse part of the CV curve for CoPc, an oxidation peak is observed, which is absent during anodic scanning, and corresponds to the cathodic reaction product. The metal complexes themselves do not oxidize under the conditions.

Keywords

cobalt, copper, phthalocyanine, trichlorophenoxy groups, electrochemistry, cyclic voltammetry.

References

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