Oxygen-Ionic Conductivity in Isovalent-Doped Layered BaLaInO4-Based Perovskites

A. O. Bedarkova; Бедарькова А. О.; P. V.  Cheremisina; Черемисина П. В.; E. V. Abakumova; Абакумова Е. В.; I. S. Fedorova; Федорова И. С.; K. G. Davletbaev; Давлетбаев К. Г.; N. A. Tarasova; Тарасова Н. А.; I. E. Animitsa; Анимица И. Е.

doi:10.31857/S0424857023040035

Oxygen-Ionic Conductivity in Isovalent-Doped Layered BaLaInO4-Based Perovskites

Authors: Bedarkova A.O.¹^,2, Cheremisina P.V.¹^,2, Abakumova E.V.¹^,2, Fedorova I.S.², Davletbaev K.G.¹^,2, Tarasova N.A.¹^,2, Animitsa I.E.¹^,2
Affiliations:
1. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Science
2. Ural Federal University named after the first President of Russia B.N. Eltsin
Issue: Vol 59, No 4 (2023)
Pages: 193-199
Section: Articles
URL: https://journals.rcsi.science/0424-8570/article/view/139258
DOI: https://doi.org/10.31857/S0424857023040035
EDN: https://elibrary.ru/ANZTXH
ID: 139258

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Abstract

The oxygen-ionic conductivity of isovalent-doped complex oxides characterized by the Ruddlesden–Popper structure is studied. The BaLa0.9Nd0.1InO4 sample was obtained for the first time by substitution in the La sublattice, and its transport properties are studied. A comparing of the results with the data for samples obtained earlier by isovalent substitution in the In-sublattice of BaLaInO4 is presented. The introducing of a dopant is shown to lead to increase in the contribution from oxygen-ionic conductivity and also in the total conductivity by ~2 orders of magnitude.

Keywords

Ruddlesden–Popper structure, BaLaInO4, isovalent doping, oxygen-ionic conductivity

References

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