Effect of Ga3+ and In3+ Ions on the Anodic Dissolution of Aluminum in KOH Ethanol Solutions
- Authors: Rybalka K.V.1, Beketaeva L.A.1
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Affiliations:
- Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
- Issue: Vol 59, No 2 (2023)
- Pages: 111-116
- Section: Articles
- URL: https://journals.rcsi.science/0424-8570/article/view/139237
- DOI: https://doi.org/10.31857/S0424857023020093
- EDN: https://elibrary.ru/NGEFCD
- ID: 139237
Cite item
Abstract
The anodic dissolution of aluminum in the KOH ethanol solutions is considered. It is shown that an addition of gallium and indium compounds to the 2 M KOH solution in 96% ethanol leads to an abrupt increase in the anodic dissolution current of aluminum near the open-circuit potential and its shift by 300 mV toward negative values. The discharge galvanostatic curves in the solutions with the additives of gallium and indium compounds contain a flat discharge plateau at the current densities up to 4 mA/cm2. The hydrogen evolution rate in a number of KOH ethanol solutions is measured.
About the authors
K. V. Rybalka
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: mamaison2000@yandex.ru
Moscow, 119071 Russia
L. A. Beketaeva
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Author for correspondence.
Email: mamaison2000@yandex.ru
Moscow, 119071 Russia
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