Effect of Ga3+ and In3+ Ions on the Anodic Dissolution of Aluminum in KOH Ethanol Solutions

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Abstract

The anodic dissolution of aluminum in the KOH ethanol solutions is considered. It is shown that an addition of gallium and indium compounds to the 2 M KOH solution in 96% ethanol leads to an abrupt increase in the anodic dissolution current of aluminum near the open-circuit potential and its shift by 300 mV toward negative values. The discharge galvanostatic curves in the solutions with the additives of gallium and indium compounds contain a flat discharge plateau at the current densities up to 4 mA/cm2. The hydrogen evolution rate in a number of KOH ethanol solutions is measured.

About the authors

K. V. Rybalka

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: mamaison2000@yandex.ru
Moscow, 119071 Russia

L. A. Beketaeva

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Author for correspondence.
Email: mamaison2000@yandex.ru
Moscow, 119071 Russia

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