A novel method for the preparation of nanosized tysonite phases

R. M. Zakalyukin; Закалюкин Р. М.; E. A. Levkevich; Левкевич Е. А.; V. V. Grebenev; Гребенев В. В.; T. Yu. Glazunova; Глазунова Т. Ю.; М. E. Buzoverov; Бузоверов М. Е.; A. S. Kumskov; Кумсков А. С.

doi:10.31857/S0367676523702411

A novel method for the preparation of nanosized tysonite phases

Authors: Zakalyukin R.M.¹^,2, Levkevich E.A.¹^,2, Grebenev V.V.¹, Glazunova T.Y.³, Buzoverov М.E.³, Kumskov A.S.¹
Affiliations:
1. Shubnikov Institute of Crystallography of Federal Scientific Research Centre “Crystallography and Photonics” of the Russian Academy of Sciences
2. MIREA – Russian Technological University
3. Moscow State University, Faculty of Chemistry
Issue: Vol 87, No 10 (2023)
Pages: 1381-1384
Section: Articles
URL: https://journals.rcsi.science/0367-6765/article/view/141830
DOI: https://doi.org/10.31857/S0367676523702411
EDN: https://elibrary.ru/WXFFZT
ID: 141830

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Abstract
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Abstract

Nanopowders of tysonite solid solutions La_{1 –} _xBa_xF_{3 –} _x (х = 0–0.07) were synthesized for the first time by thermal decomposition of lanthanum and barium trifluoroacetates. The samples obtained were characterized by electron microscopy, X-ray phase analysis, and impedance spectroscopy. Nanoparticles are crystalline and have characteristic sizes of 20–75 nm. The ionic conductivity of solid solutions in the range up to 300°C is determined by surface phenomena at the particle boundaries.

References

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