Adducts of Sterically Hindered Tellurium Catecholate with Ethers

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Abstract

Adducts of tellurium(IV) 3,6-di-tert-butyl catecholate (Te(Cat36)2) with 1,2-dimethoxyethane (Dme), bis(2-methoxy)ethyl ether (diglyme), and crown ether 18-crown-6 (18c6) ([Te(Cat36)2(Dme)]2 (I), [Te(Cat36)2(diglyme)] (II), and [Te2(Cat36)4(18c6)] (III), respectively) are synthesized and characterized by X-ray diffraction (XRD) (CIF files CCDC nos. 2208717 (I), 2208718 (II), and 2208719 (III)). The complexes are also characterized by NMR (1H, 125Te) and IR spectroscopy.

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About the authors

P. A. Petrov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Author for correspondence.
Email: panah@niic.nsc.ru
Россия, Новосибирск

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