6Ag2Se + Ag8GeTe6 ↔ 6Ag2Te + Ag8GeSe6 Reciprocal System

A. J. Amiraslanova; Амирасланова А. Дж.; A. T. Mammadova; Мамедова А. Т.; S. Z. Imamaliyeva; Имамалиева С. З.; I. J. Alverdiyev; Алвердиев И. Дж.; Yu. A. Yusibov; Юсибов Ю. А.; M. B. Babanly; Бабанлы М. Б.

doi:10.31857/S0044457X2360024X

6Ag2Se + Ag8GeTe6 ↔ 6Ag2Te + Ag8GeSe6 Reciprocal System

Authors: Amiraslanova A.J.¹, Mammadova A.T.¹, Imamaliyeva S.Z.², Alverdiyev I.J.¹, Yusibov Y.A.¹, Babanly M.B.²^,3
Affiliations:
1. Ganja State University
2. Institute for Catalysis and Inorganic Chemistry
3. Baku State University
Issue: Vol 68, No 8 (2023)
Pages: 1099-1110
Section: ФИЗИКО-ХИМИЧЕСКИЙ АНАЛИЗ НЕОРГАНИЧЕСКИХ СИСТЕМ
URL: https://journals.rcsi.science/0044-457X/article/view/136415
DOI: https://doi.org/10.31857/S0044457X2360024X
EDN: https://elibrary.ru/MLDGDG
ID: 136415

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Abstract
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Abstract

Here, we present the results of DTA and XRD studies of phase equilibria in the 6Ag2Se + Ag8GeTe6 ↔ 6Ag2Te + Ag8GeSe6 reciprocal system (system A). A Т–х diagram of the Ag8GeSe6–Ag8GeTe6 boundary system, several inner polythermal sections, isothermal sections at 300 and 1000 K, and the liquidus surface projection were plotted. The Ag8GeSe6–Ag8GeTe6 system is a partially quasi-binary system; it features continuous substitutional solid solutions between Ag8GeTe6 and the high-temperature cubic Ag8GeSe6 phase (the δ phase). Once solid solutions are formed, the polymorphic transition temperature in Ag8GeSe6 decreases, thereby stabilizing the ion-conducting cubic phase in the range of ≥40 mol % Ag8GeTe6 compositions at room temperature and below it. System A is shown to be a reversible reciprocal system; its liquidus surface is comprised of three fields, which relate to the primary crystallization of the solid solutions between the high-temperature Ag2Se and Ag2Te (α phase) phases, IT-Ag2Te-base solid solutions (β phase), and the δ phase. The subsolidus portion of system A features complex interactions related to polymorphism in the terminal compounds and in phases based on them

Keywords

silver germanium selenide, silver germanium telluride, phase equilibria, solid solution, polymorphic transformation

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