Kinetics and Dynamics of Sorption of the Glucose Target Molecule by a Molecularly Imprinted Polymer

I. S. Garkushina; Гаркушина И. С.; A. S. Panyuta; Панюта А. С.

doi:10.31857/S0044453723120117

Kinetics and Dynamics of Sorption of the Glucose Target Molecule by a Molecularly Imprinted Polymer

Authors: Garkushina I.S.¹, Panyuta A.S.¹
Affiliations:
1. Institute of Macromolecular Compounds of the Russian Academy of Sciences
Issue: Vol 97, No 12 (2023)
Pages: 1699-1706
Section: ХИМИЧЕСКАЯ КИНЕТИКА И КАТАЛИЗ
URL: https://journals.rcsi.science/0044-4537/article/view/233055
DOI: https://doi.org/10.31857/S0044453723120117
EDN: https://elibrary.ru/YQKQZR
ID: 233055

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Abstract
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Abstract

The effect of imprinting of a polymer matrix based on ethylene glycol dimethacrylate on the kinetics and dynamics of binding of the glucose target molecule has been studied. The contribution of the adsorption act to the sorption kinetics of the target sorbate by the molecularly imprinted polymer was established. Mixed-diffusion limitation of mass transfer and cooperative adsorption of glucose molecules during sorption by both imprinted and nonimprinted polymer granules were revealed. The binding rate and accessibility of sorption sites in the imprinted polymer were shown to increase, and frontal sorption occurred in a regular mode.

Keywords

mass transfer, regular mode, molecular imprinting, polymer sorbents, sorption kinetics, sorption dynamics

About the authors

I. S. Garkushina

Institute of Macromolecular Compounds of the Russian Academy of Sciences

Email: irin-g16@yandex.ru
199004, St. Petersburg, Russia

A. S. Panyuta

Institute of Macromolecular Compounds of the Russian Academy of Sciences

Author for correspondence.
Email: irin-g16@yandex.ru
199004, St. Petersburg, Russia

References

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