Fe- and Cu–Zn-Containing Catalysts Based on Natural Aluminosilicate Nanotubes and Zeolite H-ZSM-5 in the Hydrogenation of Carbon Dioxide

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Abstract

Iron- and Cu–Zn-containing carbon dioxide hydrogenation catalysts based on natural aluminosilicate nanotubes and zeolite H-ZSM-5 are synthesized. Their textural and acidic properties are studied via low-temperature nitrogen adsorption–desorption, temperature-programmed desorption of ammonia, temperature-programmed reduction of hydrogen, and elemental analysis. The effect the temperatures of the reaction have on the conversion of CO2 and distribution of its product is studied. Catalysts based on aluminosilicate halloysite nanotubes exhibit methanol and С2–С4 hydrocarbon selectivities of 88 and 16%, respectively.

About the authors

E. M. Smirnova

Gubkin State University of Oil and Gas

Email: smirnova.em94@gmail.com
119991, Moscow, Russia

N. D. Evdokimenko

Faculty of Chemistry, Moscow State University

Email: smirnova.em94@gmail.com
119991, Moscow, Russia

M. V. Reshetina

Gubkin State University of Oil and Gas

Email: smirnova.em94@gmail.com
119991, Moscow, Russia

N. R. Demikhova

Gubkin State University of Oil and Gas

Email: smirnova.em94@gmail.com
119991, Moscow, Russia

A. L. Kustov

Faculty of Chemistry, Moscow State University

Email: smirnova.em94@gmail.com
119991, Moscow, Russia

S. F. Dunaev

Faculty of Chemistry, Moscow State University

Email: smirnova.em94@gmail.com
119991, Moscow, Russia

V. A. Vinokurov

Gubkin State University of Oil and Gas

Email: smirnova.em94@gmail.com
119991, Moscow, Russia

A. P. Glotov

Gubkin State University of Oil and Gas; Faculty of Chemistry, Moscow State University

Author for correspondence.
Email: smirnova.em94@gmail.com
119991, Moscow, Russia; 119991, Moscow, Russia

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Copyright (c) 2023 Е.М. Смирнова, Н.Д. Евдокименко, М.В. Решетина, Н.Р. Демихова, А.Л. Кустов, С.Ф. Дунаев, В.А. Винокуров, А.П. Глотов

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