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Licensed Unlicensed Requires Authentication Published by De Gruyter April 18, 2019

The Effect of Ultraviolet Ageing on the Flame Retardancy, Thermal Stability and Mechanical Properties of LGFPP/IFR

  • W.-D. He , Y. Zhou , Y.-F. Wu , J.-B. Guo , X.-L. Chen and X. Zhang

Abstract

In this work, long glass fibre reinforced polypropylene/intumescent flame retardants (LGFPP/IFR) composites are exposed to ultraviolet (UV) radiation with wavelength of 340 nm for 0–800 h. The effects of UV ageing on the flame retardancy, thermal stability and mechanical properties of LGFPP/IFR composites are investigated and discussed by limiting oxygen index (LOI), UL–94 test, cone calorimeter test (CCT), thermogravimetric analysis (TGA), scanning electronic microscopy (SEM), mechanical properties and energy dispersive X-ray analysis (EDAX). A slight variation in LOI values and UL-94 levels are observed, and CCT results display a lower heat release rate for all aged samples. The TGA result also shows that aged samples have a higher degradation temperature with the prolongation of the aging time. EDAX showed higher content of the O, P and N elements on the surface of samples after 600 h ageing, which means partly gathering of IFR particles. The tensile, bending and impact strengths decrease after ageing, and the fracture morphology shows that interface debonding occurs.


*Correspondence address, Mail address: Xiaolang Chen, Key Laboratory of Advanced Materials Technology Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, PRC, E-mail:

References

Awaja, F., Nguyen, M. T., Zhang, S. N. and Arhatari, B., “The Investigation of Inner Structural Damage of UV and Heat Degraded Polymer Composites Using X-Ray Micro CT”, Composites Part A, 42, 408418 (2011) 10.1016/j.compositesa.2010.12.015Search in Google Scholar

Chen, X. L., Yu, J. and Guo, S. Y., “Structure and Properties of Polypropylene Composites Filled with Magnesium Hydroxide”, J. Appl. Polym. Sci., 102, 49434951 (2006) 10.1002/app.24938Search in Google Scholar

Enescu, D., Frache, A., Lavaselli, M., Monticelli, O. and Marino, F., “Novel Phosphorous-Nitrogen Intumescent Flame Retardant System. Its Effects on Flame Retardancy and Thermal Properties of Polypropylene”, Polym. Degrad. Stab., 98, 297305 (2013) 10.1016/j.polymdegradstab.2012.09.012Search in Google Scholar

Gavgani, J. N., Adelnia, H., Gity, M. M. S. and Zafari, F., “Intumescent Flame Retardant Polyurethane/Starch Composites: Thermal, Mechanical, and Rheological Properties”, J. Appl. Polym. Sci., 131, 243254 (2014) 10.1002/app.41158Search in Google Scholar

Griffiths, R., Ball, A., “An Assessment of the Properties and Degradation Behaviour of Glass-Fibre-Reinforced Polyester Polymer Concrete”, Compos. Sci. Technol., 60, 27472753 (2000) 10.1016/S0266-3538(00)00147-0Search in Google Scholar

Guo, G., Shi, Q. W., Luo, Y. B., Fan, R. R., Zhou, L. X., Qian, Z. Y. and Yu, J., “Preparation and Ageing-Resistant Properties of Polyester Composites Modified with Functional Nanoscale Additives”, Nanoscale Res. Lett., 9, 215223 (2014)PMid:24872802; 10.1186/1556-276X-9-215Search in Google Scholar PubMed PubMed Central

Han, Y., Xu, Y., Liu, Y., Wang, Q., Zhang, Z. J. and Wang, Z. Y., “An Efficient Interfacial Flame-Resistance Mode to Prepare Glass Fiber Reinforced and Flame Retarded Polyamide 6 with High Performance”, J. Mater. Chem. A., 1, 1022810233 (2013) 10.1039/c3ta11312dSearch in Google Scholar

He, W. D., Qi, F., Wang, N., Chen, X. L., Zhang, K. and Guo, J. B., “The Influence of Thermal Oxidative Ageing on Flame Retardancy, Thermal and Mechanical Properties of LGFPP/IFR Composites”, J. Therm. Anal. Calorim., 131, 10181024 (2018) 10.1007/s10973-017-6679-4Search in Google Scholar

He, W. D., Qi, F., Wang, N., Chen, X. L., Zhang, K. and Guo, J. B., “The Influence of Thermal Oxidative Ageing on Flame Retardancy, Thermal and Mechanical Properties of LGFPP/IFR Composites”, J. Therm. Anal. Calorim., 131, 18 (2017)Search in Google Scholar

Kalali, E. N., Juan, S. D., Wang, X., Nie, S. B., Wang, R. and Wang, D. Y., “Comparative Study on Synergistic Effect of LDH and Zirconium Phosphate with Aluminum Trihydroxide on Flame Retardancy of EVA Composites”, J. Therm. Anal. Calorim., 121, 619626 (2015) 10.1007/s10973-015-4598-9Search in Google Scholar

Kennedy, M. T., Cuellar, E. and Roberts, D. R., “Stress-Free Aging of Optical Fibers in Liquid Water and Humid Environments: Part 1 Fiber”, Fiber. Optic. Compo. Rel., 15801, 152162 (1992)Search in Google Scholar

Kumar, A., Depan, D., Tomer, N. and Singh, R., “Nanoscale Particles for Polymer Degradation and Stabilization-Trends and Future Perspectives”, Prog. Polym. Sci., 34, 479515 (2009) 10.1016/j.progpolymsci.2009.01.002Search in Google Scholar

Lindholm, J., Brink, A., Wilen, C. E. and Hupa, M., “Cone Calorimeter Study of Inorganic Salts as Flame Retardants in Polyurethane Adhesive with Limestone Filler”, J. Appl. Polym. Sci., 123, 17931800 (2012) 10.1002/app.34641Search in Google Scholar

Liu, Y., Deng, C. L., Zhao, J., Wang, J. S., Chen, L. and Wang, Y. Z., “An Efficiently Halogen-Free Flame Retardant Long Glass Fiber Reinforced Polypropylene System”, Polym. Degrad. Stab., 96, 363370 (2011) 10.1016/j.polymdegradstab.2010.02.033Search in Google Scholar

Nasir, A., Yasin, T. and Islam, A., “Thermo-Oxidative Degradation Behavior of Recycled Polypropylene”, J. Appl. Polym. Sci., 119, 33153320 (2011) 10.1002/app.32918Search in Google Scholar

Raab, M., Kotulak, L., Kolarik, J. and Pospisil, J., “The Effect of Ultraviolet Light on the Mechanical Properties of Polyethylene and Polypropylene Films”, J. Appl. Polym. Sci., 27, 24572466 (1982) 10.1002/app.1982.070270716Search in Google Scholar

Segovia, F., Ferrer, C., Salvador, M. D. and Amigo, V., “Flexural Characteristics of Sunlight-Aged Polyester Composites: Influence of Processing Variables”, J. Test. Eval., 30, 2026 (2002) 10.1520/JTE12285JSearch in Google Scholar

Segovia, F., Ferrer, C., Salvador, M. D. and Amigo, V., “Influence of Processing Variables on Mechanical Characteristics of Sunlight Aged Polyester-Glass Fibre Composites”, Polym. Degrad. Stab., 71, 179184 (2001) 10.1016/S0141-3910(00)00168-3Search in Google Scholar

Signor, A., Vanlandingham, M. and Chin, J., “Effects of Ultraviolet Radiation Exposure on Vinyl Ester Resins: Characterization of Chemical, Physical and Mechanical Damage”, Polym. Degrad. Stab., 79, 359368 (2003) 10.1016/S0141-3910(02)00300-2Search in Google Scholar

Tang, M. Q., Chen, M., Xu, Y., Chen, X. L., SunZ. D. and Zhang, Z. B., “Combustion Characteristics and Synergistic Effects of Red Phosphorus Masterbatch with Expandable Graphite in the Flame Retardant HDPE/EVA Composites”, Polym. Eng. Sci., 55, 28842892 (2015) 10.1002/pen.24180Search in Google Scholar

Thomason, J. L., “The Influence of Fibre Length and Concentration on the Properties of Glass Fibre Reinforced Polypropylene: 5. Injection Moulded Long and Short Fibre PP”, Composites Part A, 33, 16411652 (2002) 10.1016/S1359-835X(02)00179-3Search in Google Scholar

Vytenis, B., Paker, W. J., “Ignitability Measurements with the Cone Calorimeter”, Fire Mater., 11, 3143 (2010)Search in Google Scholar

Wang, X., Feng, N., Chang, S. Q., Zhang, G. X., Li, H. and Lu, H. F., “Intumescent Flame Retardant TPO Composites: Flame Retardant Properties and Morphology of the Charred Layer”, J. Appl. Polym. Sci., 124, 20712079 (2012) 10.1002/app.35253Search in Google Scholar

Wong, T. T., Tam, W. Y., Etches, J. A., Wang, W. X., Leng, J. S. and Lau, K., “Feasibility of Using ZnO/Epoxy Filled Hollowed Glass Fibres (HGFs) for UV Resistant Polymer Composites”, Mater. Lett., 128, 220223 (2014) 10.1016/j.matlet.2014.04.083Search in Google Scholar

Yan, W. X., Han, K. Q., Qin, L. L. and Yu, M. H., “Study on Long Fiber Reinforced Thermoplastic Composites Prepared by in situ Solid-State Polycondensation”, J. Appl. Polym. Sci., 91, 39593965 (2004) 10.1002/app.13627Search in Google Scholar

Zhang, D. H., Guo, J. B. and Zhang, K. Z., “Effects of Compatilizers on Mechanical and Dynamic Mechanical Properties of Polypropylene–Long Glass Fiber Composites”, J. Thermoplast. Compos. Mater., 28, 643655 (2015) 10.1177/0892705713486141Search in Google Scholar

Zhang, J., Silcock, G. and Shields, T. J., “Study of the Combustion and Fire Retardancy of Polyacrylonitrile and its Copolymers by Using Cone Calorimetry”, J. Fire. Sci., 13, 14161 (1995) 10.1177/073490419501300204Search in Google Scholar

Zhao, H. X., Li, R. K.Y., “A Study on the Photo-Degradation of Zinc Oxide (ZnO) Filled Polypropylene Nanocomposites”, Polymer, 47, 32073217 (2006) 10.1016/j.polymer.2006.02.089Search in Google Scholar

Zuo, X. L., Shao, H. J., Zhang, D. H., Hao, Z. and Guo, J. B., “Effects of Thermal-Oxidative Ageing on the Flammability and Thermal Oxidative Degradation Kinetics of Tris(tribromophenyl) Cyanurate Flame Retardant PA6/LGF Composites”, Polym. Degrad. Stab., 98, 27742783 (2013) 10.1016/j.polymdegradstab.2013.10.014Search in Google Scholar

Received: 2018-04-29
Accepted: 2018-08-09
Published Online: 2019-04-18
Published in Print: 2019-04-29

© 2019, Carl Hanser Verlag, Munich

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