Are marl-limestone alternations mainly driven by CaCO3 variations at the astronomical timescale? New insights from extraterrestrial 3He

This is a Preprint and has not been peer reviewed. The published version of this Preprint is available: https://doi.org/10.1016/j.epsl.2023.118173. This is version 1 of this Preprint.

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Authors

Pierre-Henri BLARD , Baptiste SUCHERAS-MARX , Guillaume SUAN, Blandine GODET, Jade DUTILLEUL, Taous MEZINE, Thierry Adatte

Abstract

Marl-limestone alternations are rhythmical inter-bedded deposits that commonly occur in many sedimentological environments. It is quite well established that these lithological variations originate from astronomically-driven climatic variations paced by the Milankovitch cycles of main periods 19, 23, 41, 100 and 405 ka. However, the sedimentological mechanisms involved are not clear: some models attribute these alternations to cyclic changes in the carbonate flux, while terrigenous siliciclastic input remained relatively constant. On the opposite, other models suggest that the carbonate flux was constant while the siliciclastic flux changed cyclically, or that both fluxes varied in antiphase. To disentangle these different scenarios, we collected marlstone and limestone samples from two sedimentary hemipelagic marl-limestone successions of Bajocian, Middle Jurassic (3 marl-limestone couplets over 3.4 m) and Valanginian, Lower Cretaceous (1 marl-limestone couplet over 0.9 m) from the Southern French Alps (Barles). We measured their concentrations in calcium carbonate, organic carbon, nannofossil, as well as in extraterrestrial 3He (3HeET). Carbonate contents range from 45% in marls to 86% in limestones. Importantly, the measured 3HeET concentrations of all samples remained nearly constant in the siliciclastic fractions, within uncertainties (< 20%). Hence, our results indicate that, at the astronomical timescale, sedimentation rates were mainly controlled by large changes in the CaCO3 net fluxes, leading to variable dilution of the terrigenous input. Nannofossil counting shows that pelagic CaCO3 fluxes of coccolithophores are inversely correlated to the total carbonate content along the marl-limestone alternations and represent less than 7% of the total carbonate content. Hence, in this setting, these marl-limestone alternations were driven by fluctuations in micritic CaCO3 supply from the nearby carbonate platform that variably diluted nannofossil and organic carbon particles. Finally, assuming a constant 3HeET flux of 100 pcc.cm-2.Ma-1, total 3HeET-derived sedimentation rates range from 20 to 30 m/Ma in the marl strata, while they reach up to 80 to 100 m/Ma in the limestone layers. These sedimentation rates are broadly compatible with local average rates estimated for the whole Bajocian and Valanginian stages by biostratigraphy.

DOI

https://doi.org/10.31223/X5807J

Subjects

Biogeochemistry, Earth Sciences, Geochemistry, Geology, Sedimentology, Stratigraphy

Keywords

marl-limestone alternations; extraterrestrial 3He; CaCO3; Bajocian; Valanginian; orbital forcing

Dates

Published: 2023-01-07 01:59

License

CC-By Attribution-NonCommercial-NoDerivatives 4.0 International

Additional Metadata

Data Availability (Reason not available):
6 supplementary Tables: https://ordar.otelo.univ-lorraine.fr/record?id=10.24396/ORDAR-108