粉体および粉末冶金
Online ISSN : 1880-9014
Print ISSN : 0532-8799
ISSN-L : 0532-8799
非船(Bi1/2Na1/2)TiO3を添加したPZTセラミックスの圧電特性および機械的特性
北川 賀津一豊田 丈紫北川 和夫山本 孝
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2002 年 49 巻 9 号 p. 780-786

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Fabrication conditions, piezoelectrical and mechanical properties of lead-free (Bi1/2Na1/2)TiO3 (BNT) doped PZT ceramics were investigated. For BNT as additives, decarbon dioxide of starting materials terminated to 700°C. Crystallization of BNT was induced above 600°C. The crystal phase of the sintered BNT ceramics was rhombohedral (a=3.885Å, a=90.003°). The secondary phase of Bi2TiO7 was formed by adding excess Na2O. Additon of excess Na2O promoted the sintering of BNT. For BNT doped PZT, the electromechanical coupling factor (kp) value was maintained at 60-70% of PZT with 0.5 and 1.0% BNT. The four point bending strength of BNT doped PZT specimens with 0.5 and 1.0 wt%BNT addition sintered at 1150°C was increased. The maximum value of Weibull modulus was 9.5.

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