粉体および粉末冶金
Online ISSN : 1880-9014
Print ISSN : 0532-8799
ISSN-L : 0532-8799
Sm2Fe17N3新磁石の発見
入山 恭彦今岡 伸嘉
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1996 年 43 巻 1 号 p. 59-65

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We discovered a new compound Sm2Fe17N3 in 1987 through the investigation of the structural and magnetic properties of Fe-N-X ( where X denotes an additive element ). The Sm2Fe17N3 is a new type of magnet material which is prepared by introducing nitrogen atoms into the interstitial sites of the Sm2Fe17 crystal under a nitrogen-containing atmosphere at elevated temperatures. The Sm2Fe17N3 shows excellent intrinsic magnetic properties (saturation magne-tization Ms = 1.57 T, the anisotropy field Ha = 21 MA/m and Curie temperature Tc = 746 K). The value of the theoretical maximum energy product, (BH)max amounts to 490 kJ/m3, being a match for the one of the Nd2Fe14B. We have succeeded in developing high performance Sm-Fe-N bonded-magnets; compression-molding magnet with (BH)max of 160 kJ/m3 and injection-molding magnets with 110 kJ/m3 have been fabricated so far. Mn-added Sm-Fe-N compacted powder magnet comprised of coarse powder has also been obtained. The Mn-added magnet has good thermal stability and excellent oxidation-resistance.

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