Journal of the Japan Society of Powder and Powder Metallurgy
Online ISSN : 1880-9014
Print ISSN : 0532-8799
ISSN-L : 0532-8799
Synthesis and Magnetism of X2Co12P7 (X = Group 3~5 Elements) with Zr2Fe12P7-type Structure
Kojiro TAKAHASHIHiroto OHTAMasaki KATO
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JOURNAL OPEN ACCESS Advance online publication

Article ID: 24-00015

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Abstract

To clarify the anomalous behavior of magnetization of Zr2Co12P7, we synthesized solid solution systems Zr2−xNbxCo12P7 and Zr2−yYyCo12P7 and studied their magnetism. In addition to x = 2 and y = 2, we successfully obtained polycrystalline samples in a single phase in 0 < x < 1 and 0 < y < 1. The Y-substitution did not affect the Curie temperature (TC), while the Nb-substitution decreased TC from 150 K to 30 K. The electron doping from Nb or local deformation may cause the decrease of TC. The low-temperature plateau in the temperature dependence of the magnetization expands to a higher-temperature region by the Nb-substitution. A comparison of the simulation in the two-magnetic-sublattice model and experimental results showed that the magnetic moment of Nb coupled to the ferromagnetic internal field stronger than that of Zr. Qualitative agreement between the simulation and the experiment indicated that d electrons of X are localized, and their magnetic moment couples to the ferromagnetic internal field as the case of 4f electrons of lanthanoids.

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