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BY-NC-ND 3.0 license Open Access Published by De Gruyter July 24, 2008

Dielectric properties of LC mixture with induced antiferroelectric phase

  • M. Wojciechowski EMAIL logo , G. Bąk and M. Tykarska
From the journal Opto-Electronics Review

Abstract

Mixture of two liquid crystalline components exhibits the antiferroelectric phase in a broad temperature range at room temperatures, though the two components separately do not show an antiferroelectric phase in a temperature range applied. The dielectric spectroscopy technique combined with measurements of the selective light reflection was used for identification and characterization of the phases and subphases existing in the mixture. In the SmC*A phase, the low frequency mode characteristic of antiferroelectric phase has been detected. In the broad temperature range between SmC*A and SmA* phases, no relaxation mode has been detected. The soft mode registered near the phase transition to SmA* phase follows the Curie-Weiss law.

[1] J.P.F. Lagerwall, P. Rudquist, S.T. Lagerwall, and F. Giesselmann, “On the phase sequence of antiferroelectric liquid crystals and its relation to orientational and translational order”, Liq. Cryst. 30, 399–414 (2003). http://dx.doi.org/10.1080/026782903100006968310.1080/0267829031000069683Search in Google Scholar

[2] E. Górecka, D. Pociecha, M. Cepic, B. Zeks, and R. Dąbrowski, “Enantiometric excess dependence of the phase diagram of antiferroelectric liquid crystals”, Phys. Rev. E65, 061703 (2002). 10.1103/PhysRevE.65.061703Search in Google Scholar PubMed

[3] I. Musevic, R. Blinc, and B. Zeks, The Physics of Ferroelectric and Antiferroelectric Liquid Crystals, World Scientific Publishing Co. Pte. Ltd., Singapore, 2000. Search in Google Scholar

[4] M. Buivydas, F. Gouda, S.T. Lagerwall, and B. Stebler, “The molecular aspect of double absorption peak in the dielectric spectrum of the antiferroelectric liquid crystal phase”, Liq. Cryst. 18, 879–886 (1995). http://dx.doi.org/10.1080/0267829950803670610.1080/02678299508036706Search in Google Scholar

[5] M. Buivydas, F. Gouda, G. Andersson, S.T. Lagerwall, B. Stebler, J. Bomelburg, G. Heppke, and B. Gestblom, “Collective and non-colective excitations in antiferroelectric and ferrielectic liquid crystals studied by dielectric relaxation spectroscopy and electo-optic measurements”, Liq. Cryst. 23, 723–739 (1997). http://dx.doi.org/10.1080/02678299720800010.1080/026782997208000Search in Google Scholar

[6] A. Fąfara, M. Marzec, S. Wróbel, R. Dąbrowski, and W. Haase, “Collective and molecular modes in ferroelectric and antiferroelectric liquid crystals”, IEEE T. Dielect. El. In. 8, 477–480 (2001). http://dx.doi.org/10.1109/94.93336810.1109/94.933368Search in Google Scholar

[7] B. Żywucki, W. Kuczyński, and J. Małecki, “Dielectric relaxation in liquid crystal phases with polar order”, Ferroelectrics 297, 91–105 (2003). Search in Google Scholar

[8] S. Merino, M.R. de la Fuente, Y. Gonzalez, M.A.P. Jubindo, B. Ros, and J.A. Puertolas, “Broadband dielectric measurements on the (R)-1-methylheptyl-6-(4′-decyloxybenzoyloxy)-2-naphtalene carboxylate antiferroelectric liquid crystal”, Phys. Rev. E54, 5169–5177 (1966). 10.1103/PhysRevE.54.5169Search in Google Scholar PubMed

[9] M.B. Pandey, R. Dhar, V.K. Agrawal, R. Dąbrowski, and M. Tykarska, “Study of different modes of dielectric relaxation in newly synthesized material exhibiting ferro-, ferriand antiferroelectric phases”, Liq. Cryst. 31, 973–987 (2004). http://dx.doi.org/10.1080/0267829041000170927510.1080/02678290410001709275Search in Google Scholar

[10] K. Skrzypek and M. Tykarska, “The induction of antiferroelectric phase in the bicomponent system comparising cyano compound”, Ferroelectrics 343, 177–180 (2006). http://dx.doi.org/10.1080/0015019060096239010.1080/00150190600962390Search in Google Scholar

[11] M. Wojciechowski, L.A. Gromiec, and G.W. Bąk, “Dielectric characteristics of chiral smectic C subphases in liquid crystal MHPOPB”, J. Mol. Liq. 124, 7–12 (2006). http://dx.doi.org/10.1016/j.molliq.2004.12.00410.1016/j.molliq.2004.12.004Search in Google Scholar

[12] M.B. Pandey, R. Dąbrowski, and R. Dhar, “Investigation of relaxation processes in anticlinic smectic C* (SmC*A) phase of liquid crystals by dielectric spectroscopy”, Physica B387, 25–31 (2007). 10.1016/j.physb.2006.03.023Search in Google Scholar

[13] S. Kundu, T. Ray, S.K. Roy, and R. Dąbrowski, “Experimental characterization of hexatic smectic phases through electro-optics studies and dielectric relaxation spectroscopy”, Liq. Cryst. 31, 119–125 (2004). http://dx.doi.org/10.1080/0267829041000166605710.1080/02678290410001666057Search in Google Scholar

Published Online: 2008-7-24
Published in Print: 2008-9-1

© 2008 SEP, Warsaw

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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