Abstract
Starting from the paddlewheel complex copper(II)acetate, the green N-methylimidazole adduct of copper(II)acetate is formed and transformed into the monomeric and dimeric N-methylimidazole adducts of copper(II)acetate [Cu(C4H6N2)2(CH3COO)2]n·xH2O (n = 1,2; x = 0, 6). The formation of the blue dimer or the purple monomer depends on the solvent and the presence or absence of water.
[1] F. Wöhler, J. Liebig, Ann. Pharm. 3, 249 (1832) http://dx.doi.org/10.1002/jlac.1832003030210.1002/jlac.18320030302Search in Google Scholar
[2] J. Thun, L. Seyfarth, J. Senker, R.E. Dinnebier, J. Breu, Angew. Chem. Int. Ed. 46, 6729 (2007) http://dx.doi.org/10.1002/anie.20070138310.1002/anie.200701383Search in Google Scholar
[3] J.W. Pflugrath, Acta Cryst. 55D, 1718 (1999) 10.1107/S090744499900935XSearch in Google Scholar
[4] P.R. Evans, Acta Cryst. 62D, 72 (2005) 10.1107/S0907444905036693Search in Google Scholar
[5] G.M. Sheldrick, Acta Cryst. 64A, 112 (2008) 10.1107/S0108767307043930Search in Google Scholar
[6] P.Y. Boukari, A. Busnot, F. Busnot, A. Leclaire, M.A. Bernard, Acta Cryst. B38, 2458 (1982) 10.1107/S0567740882009030Search in Google Scholar
[7] O. Kühl, G. Palm, Tetrahedron: Asymmetry 21, 393 (2010) http://dx.doi.org/10.1016/j.tetasy.2010.02.01510.1016/j.tetasy.2010.02.015Search in Google Scholar
[8] N.N. Greenwood, A. Earnshaw, Chemistry of the Elements (Pergamon Press, Oxford 1989) Search in Google Scholar
[9] N. Wiberg, Hollemann-Wiberg, Lehrbuch der Anorganischen Chemie, 91st–100th editions (Walter der Gruyter, Berlin, 1985) (In German) 10.1515/9783110838176Search in Google Scholar
[10] I.B. Bersuker, Coord. Chem. Rev. 14, 357 (1975) http://dx.doi.org/10.1016/S0010-8545(00)80266-010.1016/S0010-8545(00)80266-0Search in Google Scholar
[11] J.N. Van Niekerk, F.P.L. Schoening, Nature 171, 36 (1953) http://dx.doi.org/10.1038/171036a010.1038/171036a0Search in Google Scholar
[12] A. Werner, Ann. Chem. 375, 1 (1910) 10.1002/jlac.19103750102Search in Google Scholar
[13] F.A. Cotton, G. Wilkinson, Advanced Inorganic Chemistry (John Wiley & Sons, Chichester, 1988) Search in Google Scholar
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