In this study, Substituent variations Sulfilimines were prepared from sulfides and chloramine T and the delayed action in vulcanization was examined for sulfur cure and peroxide cure. The result showed that as it was already reported the sulfilimine with β-hydrogen(No.5) was effective inhibitor for sulfur cure. And it was proven that the sulfilimine with β-hydrogen (No.5) showed effect as scorch reterder for peroxide cure. This is supposed that the sulfilimine which would prove from the result of PGC-MS decomposes thermally, and olefin is formed. Therefore, it is supposed showing the effect. It seems to be effective for sulfur cure and peroxide cure combined system because the sulfilimine with β-hydrogen has delayed action in vulcanization both sulfur cure and peroxide cure.