Transactions of the Japan Institute of Metals
Online ISSN : 2432-4701
Print ISSN : 0021-4434
ISSN-L : 0021-4434
Transformation Behavior of ZrO2-2.5 mol%Y2O3 Compact during Cyclic Annealing
Noboru YoshikawaHajime Suto
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1985 Volume 26 Issue 4 Pages 280-287

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Abstract

It is well known that the stress induced martensitic transformation is responsible for the high strength of partially stabilized zirconia (PSZ). In the present study, conventionally sintered (CS) and hot-pressed (HP) commercial PSZ compacts with 2.5 mol% Y2O3 were used as original materials. After annealed at various temperatures, transformation behaviors during cyclic annealing were investigated by dilatometory. In addition, bending test was carried out for HP specimens subjected to cyclic annealing. The results are as follows: (1) The dominant constituent phases in as-received and as-annealed specimens were tetragonal and cubic, except a few cases. (2) The tetragonal phase (t-ZrO2) in as-received PSZ was stable up to 1573 K. But in the specimens pre-annealed at higher temperatures, the retained t-ZrO2 transformed to the monoclinic phase (m-ZrO2) at about 500 K, and then transformation from monoclinic to tetragonal (m-t) took place at about 850 K on the first heating. This t-ZrO2 easily transformed to m-ZrO2 at about 700 K on the subsequent cooling. (3) The stability of t-ZrO2 in as-annealed specimens is influenced by the segregation of Y in the original state. (4) The mean value of transverse rupture strength of HP–PSZ was decreased by thermal cycles of 100 times up to 1553 K.

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