doiSerbia

Arsenate and arsenite adsorption in relation with chemical properties of alluvial and loess soils

Rukh Shah (PMAS-Arid Agriculture University, Department of Soil Science & SWC, Rawalpindi, Pakistan)
Akhtar Saleem Mohammad (PMAS-Arid Agriculture University, Department of Soil Science & SWC, Rawalpindi, Pakistan)
Mehmood Ayaz (University of Haripur, Department of Agricultural Sciences, Haripur, Pakistan)
Hassan Sayed (University of Georgia, Department of Crop and Soil Sciences, Athens, USA)
Khan Khalid S. (PMAS-Arid Agriculture University, Department of Soil Science & SWC, Rawalpindi, Pakistan)
Naqvi Syed M.S. (PMAS-Arid Agriculture University, Institute of Biochemistry and Biotechnology, Rawalpindi, Pakistan)
Imran Muhammad (PMAS-Arid Agriculture University, Department of Soil Science & SWC, Rawalpindi, Pakistan)

Arsenic is one of the most toxic elements in the soil environment. Understanding of the arsenic adsorption chemistry is essential for evolving the extent of soil and groundwater contaminations. This research was conducted to determine the variation in adsorption behaviour of arsenite and arsenate with depth in different lithology soils. We sampled two parent materials at genetic horizons, and within a parent material, we selected two soils. Besides basic soil characterizations, a laboratory batch experiments were carried out to study the adsorption of arsenate and arsenite. Freundlich adsorption approaches were employed to investigate the adsorption of arsenate and arsenite in the soils. Freundlich isotherms fit arsenate and arsenite sorption data well with r2 values of 0.88–0.98 in most soils. Arsenate and arsenite adsorption varied with the soil properties, especially in clay composition and in the oxides of iron and aluminum. Arsenic adsorption parameters also varied with depth in parent materials, and loess derived soils had greater adsorption capacity as compared to alluvial soils in most of the adsorption parameters. This research concludes that the loess soils had higher arsenic adsorption capacity than the alluvial soils.

Keywords: arsenic species, parent material, Freundlich isotherm