Hemijska industrija 2013 Volume 67, Issue 3, Pages: 437-441
https://doi.org/10.2298/HEMIND120611085V
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Volatile compounds in medlar fruit (Mespilus germanica L.) at two ripening stages
Veličković Milovan M. (Faculty of Agriculture, Belgrade)
Radivojević Dragan D. (Faculty of Agriculture, Belgrade)
Oparnica Čedo Đ. (Faculty of Agriculture, Belgrade)
Nikićević Ninoslav J. (Faculty of Agriculture, Belgrade)
Živković Marijana B. (Institute for Chemistry, Technology and Metallurgy, Belgrade)
Đorđević Neda O. (Institute for Chemistry, Technology and Metallurgy, Belgrade)
Vajs Vlatka E. (Institute for Chemistry, Technology and Metallurgy, Belgrade)
Tešević Vele V. (Faculty of Chemistry, Belgrade)
Medlar is the fruit of Mespilus germanica L. in the family of Rosaceae. The
fruit can be eaten only if ‘bletted’ (softened by frost or longer storage).
The effect of the maturation stages on the volatile compounds of the medlar
fruit was investigated during two different stages. Volatile flavour
substances were isolated from the minced pulp of unripe and full ripe medlar
fruits by simultaneous steam distillation extraction (SDE) with methilen
chloride as the extracting solvent. The concentrate was analysed by
GC-FID-MS. Hexanoic and hexadecanoic acids were the predominant acids,
hexanal and (E)-2-hexenal were the predominant aldehydes, (Z)-3-hexenol and
hexanol were the predominant alcohols, with p-cymene, terpinen-4-ol, and
γ-terpiene (the terpenes responsible for the characteristic medlar flavour)
being also present. The C6 aliphatic compounds, such as hexanal and
(E)-2-hexenal, were observed as the major volatile constituents in the green
stage. In contrast, hexanol and (Z)-3-hexenol were the main volatiles in ripe
fruits.
Keywords: medlar, flavor, ripening, GC/MS